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Picture for Severe microbiologically influenced corrosion (MIC) of pure zinc and galvanized steel in the presence of Desulfovibrio vulgaris
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Severe microbiologically influenced corrosion (MIC) of pure zinc and galvanized steel in the presence of Desulfovibrio vulgaris

Product Number: 51320-14537-SG
Author: Di Wang, Tuba Unsal, Tingyue Gu, Sith Kumseranee, Suchada Punpruk
Publication Date: 2020
$20.00

Zinc and its alloys are used as sacrificial anodes because zinc is an active metal. Carbon steel can be coated with zinc to protect against corrosion. These metals are known as galvanized steel. In this work, microbiologically influenced corrosion (MIC) of pure zinc and galvanized steel caused by a sulfate reducing bacterium was investigated. After 7 days of incubation in 125 mL anaerobic vials with 100 mL culture medium and 1 mL inoculum, the sessile cell count on the galvanized steel was slightly higher than that on pure zinc. The abiotic weight loss for pure zinc was 1.4 ± 0.1 mg/cm2 vs. 4.6 ± 0.1 mg/cm2 for galvanized steel after 7 days of anaerobic incubation at 37oC. The weight losses for galvanized steel and pure zinc were 31.5 ± 2.5 mg/cm2 and 35.4 ± 4.5 mg/cm2, respectively, which were 10X larger than the previously reported carbon steel weight loss in the same SRB broth. Electrochemical corrosion tests confirmed the severe corrosion of these two metals. The corrosion current densities of galvanized and pure zinc were 25.5 µA/cm2 and 100 µA/cm2, respect􀀀vely at the end of the 7-day incubation with SRB, confirming that pure zinc was more prone to SRB MIC than galvanized steel. In both cases, the corrosion product was mainly ZnS. Three MIC mechanisms were possible for the severe corrosion. Extracellular electron transfer MIC is thermodynamically favorable for Zn. Furthermore, the detection of H2 evolution in the vials suggest that proton attack and H2S attack occurred against Zn in the SRB broth with neutral pH after passive film damage by the SRB biofilm. 

Picture for Shale Gas Production Pipeline Failure - Case Study
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Shale Gas Production Pipeline Failure - Case Study

Product Number: 51324-20698-SG
Author: Feras El Yaakobi; Sherman Kung; Connor Graham; Jeannine Schmid; Daryl Foley
Publication Date: 2024
$40.00
Picture for Shortcomings regarding the Testing of Oil and Gas Corrosion Inhibitors
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Shortcomings regarding the Testing of Oil and Gas Corrosion Inhibitors

Product Number: 51324-20823-SG
Author: Alyn Jenkins; Khoa Ky; David Orta
Publication Date: 2024
$40.00
Laboratory selection of oilfield corrosion inhibitors used to mitigate carbon dioxide (CO2) and hydrogen sulfide (H2S) corrosion is an essential aspect of every asset integrity program implemented in oil and gas fields. However, many factors increase the complexity of designing a corrosion inhibitor laboratory test program that will deliver reliable results. Several of these factors relate to the challenges of accurately replicating field conditions in the laboratory, including using inhibitor-free crude oil, reproducing pipeline flow regimes and wall shear stress, duplicating the specific form of corrosion that occurs in the field, and simulating inhibitor deliverability and transport in multiphase pipelines. Other elements that increase the difficulty relate to requirements for environmentally acceptable chemistries in certain geographies and the variety of corrosion performance tests and methodologies mandated by different oil companies. After the laboratory testing is complete and a corrosion inhibitor has been selected for field application, optimization of the product in the field should be performed but this is frequently overlooked. If corrosion inhibitor treat rate is not optimized in the field, it can result in overdosing (causing stabilization of emulsions and foaming) or underdosing (which can result in high corrosion rates). This paper discusses the challenges and inconsistencies associated with selecting corrosion inhibitors for use in oil and gas fields. Importantly, this paper discusses how these challenges can be resolved to ensure that the selection of oil and gas corrosion inhibitors follows a reliable process.
Picture for Silica Nanocapsules Based On Gemini Surfactant As Environmentally Friendly Nanocontainers For Corrosion Protection In Seawater
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Silica Nanocapsules Based On Gemini Surfactant As Environmentally Friendly Nanocontainers For Corrosion Protection In Seawater

Product Number: 51321-16741-SG
Author: O. Kaczerewska; J. Fikgueiredo; S. Loureiro; I. Sousa; R. Martins; J. Tedim
Publication Date: 2021
$20.00
Picture for Silica Solubility in High Enthalpy Water up to 440°C in the Presence of NaCl
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Silica Solubility in High Enthalpy Water up to 440°C in the Presence of NaCl

Product Number: 51324-21029-SG
Author: Morten Tjelta; Sissel Opsahl Viig
Publication Date: 2024
$40.00
In geothermal energy production, precipitation/scaling and potential plugging of wells is one of the major threats to flow assurance. Mitigation strategies should be considered at the design stage, but to do so knowledge about solubility across a relevant space of temperature, pressure and fluid composition is needed. In hot fluids, silica scaling is often found to be the major concern. Predictive models available in literature give good agreement with experimental values in the region where data are available, but there is limited data available at high temperatures and low pressures, in particular in the presence of salt. This work describes an experimental setup designed to carry out solubility experiments up to 500 °C and 400 bar. A main feature of the setup is the ability to dilute the sample fluid in the hot zone in order to avoid precipitation during sampling. Illustrations are given for how existing phase relations can be used to guide the execution of such high-pressure high-temperature experiments. Results of silica solubility experiments in the presence of NaCl up to 440 °C at 150-350 bar are presented. This work includes data at the steam side pseudocritical line (critical density isochor) where limited data is available in the literature. The experimental concept, with hot zone dilution to avoid precipitation during sampling, can be used to obtain fluid samples as a function of time. Although utilized in the current work for solubility experiments it should be equally applicable to corrosion studies.
Picture for Slurry Abrasion Failure Of A Carbon Steel Pipe Carrying Bitumen Froth In Oil Sands
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Slurry Abrasion Failure Of A Carbon Steel Pipe Carrying Bitumen Froth In Oil Sands

Product Number: 51321-16941-SG
Author: Reinaldo J Chung; Naveen Prathap; Shawn Chen; Jiaren (Jimmy) Jiang; Darren Ting; Marilin Garcia
Publication Date: 2021
$20.00