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Picture for On-Line Real Time Electrochemical Corrosion Monitoring in Low Conductivity Fluids – Sulfolane Aromatic Extraction – Part 2
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On-Line Real Time Electrochemical Corrosion Monitoring in Low Conductivity Fluids – Sulfolane Aromatic Extraction – Part 2

Product Number: 51319-13153-SG
Author: Slawomir Kus
Publication Date: 2019
$20.00

On-line real time corrosion monitoring in processes featuring low conductivity fluids akin to sulfolane aromatic extraction have represented a challenge for traditional electrochemical techniques. Sulfolane specific conductance that is typically about 5mS/cm enables proper determination of corrosion current with standard Linear Polarization Resistance (LPR) technology. Other electrochemical techniques such as Electrochemical Impedance Spectroscopy (EIS) or Zero Resistance Ammetry (ZRA) are useful mostly in laboratory practice but offer little or no utility for field-operational regime. Therefore corrosion processes in sulfolane units are mostly monitored by time-lagging techniques like electrical resistance (ER) and corrosion coupons or by purely qualitative approaches utilizing sulfolane color as the “corrosion indicator”.The authors’ earlier work on multi-electrochemical industrial corrosion monitoring technique integrating impedance measurement Electrochemical Noise (ECN) and Harmonic Distortion Analysis showed demonstrable efficacy in fast and accurate determination of instantaneous corrosion rate in low-conductivity sulfolane solutions. Initial data generated showed that properly adjusted surface area of the electrode facilitates attainment of stable corrosion trends in sulfolane solutions at conductance of about 2-5 mS/cm. Rapid response of the sensor to process changes (temperature oxygen water) in both general and localized modes was also observed.The current paper provides additional data and insights from the authors’ continuing research on sulfolane corrosivity utilizing industrial-type corrosion sensors. Results from comprehensive evaluation of properties of the aqueous phase as well as other relevant process parameters on general and localized corrosion of ferrous metallurgy in sulfolane applications are presented in this paper. Keywords: on-line corrosion monitoring electrochemical sulfolane aromatic extraction

Picture for Online Seam Treatment of ERW pipes for proper material selection, process control and toughness improvement
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Online Seam Treatment of ERW pipes for proper material selection, process control and toughness improvement

Product Number: MPWT19-14408
Author: C. Cincunegui, M. Coloschi, P. Marino, E. Martínez, and M. Valdez
Publication Date: 2019
$0.00

Electric Resistance Welded (ERW) pipes X60M / X65M API 5L PSL2, with resistance to ductile fracture propagation as per API 5L PSL2 Annex G [1] are achieved not only by setting the proper welding parameters and the steel cleanliness, but also by a combination of metallurgical processes affecting the final weld line and HAZ microstructure. The steel chemistry is the starting point to minimize the presence of inclusions, central segregation and the toughness impairment due to harmful elements, S, P, etc. on the pipe body, with a given casting and rolling technology. During the welding process, the right parameters combination is needed to avoid cold weld, penetrators, and other weld imperfections. At the last stage, the Seam Heat Treatment (SHT) has to be adjusted in a way that the steel response to the thermal cycles leads to the compliance of mechanical requirements at the weld line and Heat Affected Zone (HAZ). This heat treatment is performed through electromagnetic induction using several coils, which allows it to have a rapid and localized heating of the HAZ into the austenitic region, and that is followed by air cooling. The objective is to refine the structure and to eliminate brittle constituents around the weld line. As the SHT strongly affects the weld performance, the optimum processing conditions such as austenitization temperature and cooling rate may not be the same for all steel chemistry, and has to be carefully selected. The capability to model the thermal cycle after the ERW process and the understanding of the metallurgical behavior of different steel chemistries and dimensional configuration becomes the main target of any ERW pipe manufacturer aiming supply reliable Line Pipes as per API 5L PSL2 Annex G. In this work, a numerical thermal model of the SHT is presented along with validation and simulation results. A summary of metallurgical thermal cycle simulations by means of a Gleeble® 3500, applied on different steels is also included.

Picture for Onset Of Corrosion Rate Retardation At Very Low Concentrations Of H2S In A CO2 Environment
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Onset Of Corrosion Rate Retardation At Very Low Concentrations Of H2S In A CO2 Environment

Product Number: 51321-16676-SG
Author: A. Cutright; B. Brown; S. Nesic; M. Singer; D. Young
Publication Date: 2021
$20.00