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Corrosive environmental media may lead to a significant degradation of the mechanical properties of the materials. Individual experimental investigation and analysis concepts are available at the Institute of General and Analytical Chemistry for the evaluation of different materials under pressurized hydrogen. Hydrogen technologies will enable decarbonization.
Electrochemical energy conversion devices, such as fuel cells and electrolyzers, are widely recognized as an essential component of the transition to a low carbon economy. Polymer electrolyte membrane (PEM) variants of both technologies show particular promise due to their high current density, fast start-up times and low gas crossover rates. The main barrier to widespread uptake of these devices is their capital cost, which includes both raw material and manufacturing costs.
Crack growth rate properties are used to assess life and integrity to determine appropriate operating conditions and service life; permissible flaw sizes; and defining minimum detectable flaw size requirements for non-destructive evaluations (NDE). In corrosion-fatigue environments, it is important to characterize the corrosion-fatigue crack growth behavior at a frequency that allows maximum interaction between the material and the environment to ensure that test conditions are suitably representative of service conditions and appropriately conservative.
A crucial step in qualifying a material for use in a critical engineering application in oil and gas production is quantifying the effect of test frequency on the FCGRs of the material in a representative environment.
The precipitation of calcium sulphate dihydrate (CaSO4.2H2O gypsum) was studied at 25 ° C at constant calcium ion activity. The stability domain of the system and the kinetics of spontaneous precipitation of gypsum from unstable supersaturated solutions was investigated. The rates of precipitation showed parabolic dependence on the relative supersaturation in agreement with literature reports for lower supersaturations and seeded growth. Moreover the kinetics of precipitation of gypsum at sustained calcium ion activity at 25 ° C pH 6.5 were measured in the presence of two phosphonates: benzo (135-triyltrisphosphonic acid (BTP) and 135-triazine triphosphonate (TATPA) over a range of concentrations between 4-16 ppm. The presence of TATPA resulted in significant reduction of the rate of gypsum precipitation which reached total suppression of nucleation and growth at the highest test concentration. BTP showed also inhibition effect which was however lower. The differences in inhibition efficiency are attributed to molecular characteristics including flexibility and hydrogen bonding capacity.
Geothermal fluid pipelines experience temperature changes on startup and shutdown that can be of the order 300 °C. Carbon steel pipeline design can include expansion loops and direction changes to allow for thermal expansion and contraction for the long lengths of pipeline commonly used from geothermal production wells to the geothermal power station and from the station to reinjection wells. In some instances, expansion compensators are used where there is insufficient area for such loops or where the pipe diameter is prohibitively large.
Precipitation Hardened (PH) Nickel alloys have been widely used in the Oil & Gas Industry for decades as these materials offer high strength and outstanding corrosion resistance in aggressive environments. They are commonly used in high-strength components in downhole wellhead subsea and Christmas tree equipment. However high profile failures of equipment have occurred including tubing hangers cross-overs and subsea bolts with alloys such as UNS N07718 UNS N07716 or UNS N07725. In all these cases the mechanism identified was Hydrogen Assisted Cracking (HAC) as the result of the interaction between atomic hydrogen adsorbed by the alloy and its microstructure.PH Nickel alloys are all subject to precipitation of secondary and tertiary phases which if processed improperly (particularly during hot working and heat treatment) may adversely affect the material properties required for the intended application. Despite the number of scientific and technical contributions produced over the last years the interaction between these complex microstructural features and atomic hydrogen is still not understood and is further complicated by variations in testing approaches used to simulate severe hydrogen charging conditions. The present paper provides insights on the HAC failure mechanism for API 6ACRA PH Nickel alloys comparing findings from numerous studies. In addition implications for currently adopted standards and emerging specifications are also presented and discussed.