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In the present study, corrosion tests were performed using both weight loss and electrochemical techniques for Ni-Cr-Mo (W) alloys in hydrochloric (HCl), sulfuric (H2SO4), nitric (HNO3) acids and their various combinations.
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This paper describes some of the materials and process challenges facing geothermal energy developers targeting efficiency improvements and extremes of aggressive geothermal fluid chemistries and temperatures.
Internal coatings stress (ICS) develops in coatings applied to a rigid substrates. During drying, volume changes due to solvent loss and/or cure induces stresses in the films. Differences in the thermal expansion coefficients of the coating and substrate also affect the ICS. ICS affects the interfacial adhesion and results in delamination once the stress exceeds the force of adhesion.
High-strength steel is one of the basic materials for supporting a well-functioning society. Prestressed concrete (PC) is a typical example of a material in which high-strength steel is used. In PC, tensile stressed steel is embedded inside the concrete, and internal bars apply compressive stress to the concrete for preventing cracks in concrete that is vulnerable to tensile stress. Moreover, corrosion inside the steel is suppressed by the alkaline environment in the concrete, so the concrete and internal bars basically work to compensate for each other's weaknesses.
LIBS is a type of optical emission spectroscopy used to measure elemental concentrations in a material. LIBS operates by using a pulsed, focused laser that is fired at a sample with sufficient pulse energy as to create a plasma around the area struck. Bound atomic electrons are stripped from the atoms comprising the material. As the plasma cools, atoms recombine with electrons and in the process emit light in the UV, optical and IR regimes.
As known, ISO 15589-1 and SP0169 protection criteria refers to IR-Free potentials values to be met by applying cathodic protection to limit corrosion rate and, at the same time, to avoid overprotection: in this respect, according to the type of currents influencing the metallic structure, European standard EN 13509 proposes different measurement techniques for measuring IR Free potential.
This paper deals with the issue of surface contaminates analyses presently available on the market. The amount of variations of analyses and more important statements of the results cause great problems on the market. Described in the paper are not only the analyses possible, but also the interpretations belonging to them. However, salt measurements are used worldwide, its basics often appear to be a worldwide mystery. This paper should clarify the most common made mistakes.
The mechanism of carbonic acid corrosion is of a paramount importance for the oil industry. This is because production of crude is always accompanied by CO2 and water. Carbonic acid localized corrosion is by far more important than general corrosion. This is because you just need one tiny rupture in the pipe to have a failure which will need to be addressed and repaired. Methods to determine localized corrosion are very few. In one method the electrochemical potential of the metal specimen is increased with time until the material fails which is detected as a large oxidation current. In another a large constant oxidative potential is imposed on the metal coupon then its temperature is increased until a high current is observed. In both the nature of the surface at corrosion potential is not preserved. Electrochemical noise has come to address this problems because this method does not perturb the surface of the metal and all its measurements occurs at open circuit potential. However this non-perturbative method has little quantitative value and the interpretation of the data obtained is still very difficult. For instance the noise current cannot be integrated to know the extension of the damage. This is because one does not know to what electrode the noise belongs. In this paper the localized carbonic acid corrosion of a carbon steel at corrosion potential was measured. This was performed by pulsing at the corrosion potential and changing the temperature of the test. Electrochemical impedance spectroscopy was also used in the same manner. In both methods the localized current was integrated and the localized damage was determined.Key words: Localized corrosion CO2 corrosion electrochemical methods.