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Carbon capture and storage (CCS) are technologies aimed at capturing CO2, followed by transportation to a storage site and injection into one of several types of stable geological formations, to trap and prevent its subsequent emission. Though CO2 transport and injection for Enhanced Oil Recovery (EOR) are known for over 40 years, new challenges arise when the CO2 source is anthropogenic, meaning with a human-cause origin and not natural (as in EOR). EU Directive 2009/31/EC states that CO2 streams from power stations or industrial plants "shall consist overwhelmingly of CO2" but may contain associated incidental substances (e.g., SOx, NOx, O2, H2S).
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The goal of the Paris Agreement is to limit global warming to below 2°C, preferably 1.5°C, compared to pre-industrial levels.1 While the world is slowly transitioning to more sustainable energy sources to reach this target, one of the ways to reduce the CO2 in the atmosphere is to capture it and store it in depleted gas fields. According to the IOGP1, the total number of CCS projects in Europe is 65 in 2022.2 The aim of these projects is to store around 60 MtCO₂/yr by 2030.
This paper will provide recent corrosion data for stored chemicals. Duplex stainless steel corrosion curves obtained in nitric, sulfuric, phosphoric acids as well as several kinds of waters will be provided. In addition, atmospheric corrosion data obtained after 15+ years of sample exposures in several geographic areas will be shown. These results will be compared to those obtained with other materials commonly used for the construction of storage tanks.
In gas wells, where a low or unknown amount of the naturally occurring saline formation water is expected to be produced, tubing material selection relies on selecting a fixed dataset of input parameters and extrapolating to the entire well life. This is intended to represent the worst-case scenario; while this can be the case regarding pressure and temperature, the produced water composition as a function of time is less likely to be as reliable. This is because during production, gas can cause water evaporation, leading to a significant increase in the chloride ion concentration compared to the analyzed values – and hence, potentially an unsuitable material selected. To this end, it is important to: (a) ensure that the formation water composition analyzed is correct, (b) that this composition is reconciled to initial reservoir conditions and (c) calculate any evaporation/condensation effects in different sections of the well as a function of production forecasts. This makes it easier to establish operational envelopes that both prevent productivity impairment and provide appropriate thresholds of acceptability for the tubing material selected. This paper describes the methodology applied for tubing material selection for a high temperature-high pressure (HTHP) gas well in the North Sea.
Two surveys were conducted in 2011 to understand the industry knowledge and experience with respect to the use of biodiesel. This paper summarizes the salient features from these surveys.
Acid stimulation is a growing practice in the deep water subsea environment. Two acids were tested, one of hydrofluoric and acetic acids and another of hydrofluoric, hydrochloric, and acetic acids. Results and outlines recommendations for different alloys are presented.
The storage and transportation of biofuels continue to be of interest. Material compatibility issues arise. For alcohol fuels, stress corrosion cracking of steels, and swelling and leaching of various polymeric materials. This paper will provide an overview of research that has been conducted in alcohol fuels.
Integrity of materials in Oil & Gas production wells is critical to meet the objectives of design and the lifecycle performance of wells. This is significant value both in economic terms and health safety and environment. Subsurface uncertainties Aging fields EOR activities and also the quality of procured equipment add to the difficulties in preventing equipment failures in wells. Failures that are especially unforeseen or unanticipated provide crucial feedback to operators and lessons to be learnt. It is imperative for operators to learn improve processes and avoid recurrence of failures.Petroleum Development Oman (PDO) as a large operator with more than 10000 wells has gained important experience and lessons from many such failures. This has contributed significantly to improve the company standards material selection reset the operating envelope and procedures enhance surveillance and improve upon quality assurance and control of new equipment.This paper is a compilation of some of the important lessons learnt from such incidents in the recent past. It discusses the operational experience and learning from different subsurface materials from CS to nickel alloys used in different components such as casing tubing packers and X-trees.
Nickel-based alloys containing optimum amounts of chromium (Cr) molybdenum (Mo) and tungsten (W) are widely used in the chemical process industries due to their tolerance of both oxidizing and reducing conditions. In the present study corrosion tests were performed using weight loss and electrochemical techniques for Ni-based CRAs in various corrosive solutions. The motivation of this study is to understand thematerials performance in oxidizing acid (such as nitric acid) and acidic solutions containingoxidants (like ferric ion cupric ion peroxide etc.). An attempt was further made to correlate the corrosion performance of the alloys in individual and mixed acids to their alloying elements and contents.The corrosion data suggest that in oxidizing acid reducing + oxidizing acid and in solutions containing oxidants HASTELLOY® G-35® (UNS N06035) (Ni-33Cr-8Mo) exhibits a remarkably high corrosion resistance than existing nickel and iron-based alloys.