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The Hanford Site stores over 50 million gallons (190 million liters) of legacy nuclear process waste that was generated from plutonium separations and waste management processes. This waste, in the form of supernatant liquids, saltcakes, and sludges is contained in large underground storage tanks, up to a million gallons (3.78 million liters) in capacity and lined with carbon steel. The waste was made highly alkaline to ensure passivation of the carbon steel, but it also contains nitrate, in high concentrations, along with fluoride and chloride that poses risks for stress corrosion cracking and pitting corrosion.
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Subsea Global Solutions (SGS) it a worldwide provider for underwater ship repair and maintenance.During a 2.5 year long extensive joint research and development program with DNV GL it was proventhat underwater wet welds meeting the class A requirements of AWS D3.6-Underwater Welding Codecan be produced. AWS D3.6 Class A welds are comparable to out of the water welded joints. Today,SGS has approval from DNV GL and from ABS to perform permanent underwater wet weld repairs onvessels and offshore installations.This paper will discuss two applications of permanent underwater wet weld repairs performed on acruise ship and on a Floating Production Storage Offloading (FPSO) vessel. The paper is co-authoredby ABS, who will provide class opinion on underwater wet welds
Often coatings are judged by certain criteria especially when it comes to immersion service. One of the criteria used to evaluate these coatings is permeability, which is often misunderstood. With 2 ASTM test methods, each with multiple methods and ways to report the results, you may get so much conflicting information that none of the information permeates into your brain in an understandable way.
Duplex stainless steels (DSS) are widely used as structural alloys in marine and energy industries because of their excellent combination of mechanical properties and corrosion resistance. In light water reactor (LWR) power plants, these alloys find their applications in piping and internal structural components. With a currently designed lifetime of 40 years, these DSS components show little degradation in their mechanical properties. However, most current and future nuclear power plants are expected to operate beyond 60 years. This prolonged service period challenges the integrity of materials and components in the reactor. DSS component lifetime in the reactor is subjected to elevated temperatures, internal pressures, and corrosive environments.
The Phenylalanine based corrosion inhibitor 13-bis(1-carboxy-2-phenylethyl)-5-methyl-1H-imidazol-3-ium (IP) were synthesized by the condensation of phenylalanine glyoxal and formaldehyde and characterized by the FTIR and NMR spectroscopy. The corrosion inhibition performance of synthesized inhibitor was studied by electrochemical impedance spectroscopy (EIS) potentiodynamic polarization (PDP) Surface and DFT methods. The results show the studied IP is an effective inhibitor showed the maximum inhibition efficiency of 96.08% at concentration 200ppm. The results of PDP study revealed that IP act as mixed type inhibitor. The results of EIS studies showed that IP inhibits the mild steel corrosion through adsorption mechanism. The adsorption of synthesized phenylalanine derived Zwitterion on the mild steel surface was followed the Langmuir adsorption isotherm. The formation of inhibitor film on mild steel surface was confirmed by the scanning electron microscope (SEM) and energy-dispersive X-ray spectroscopy (EDX). The quantum chemical parameters were used to study the reactivity of IP inhibitor with iron surface. An inhibitor adsorption model is proposed.
Pipeline Owners use the HDD installation method primarily in high consequence areas. The pipelines are thrust into the ground in one of the harshest possible manners which ultimately puts the protective coatings to the test. The manner that the Pipelines are coated and tested is governed by PHMSA. This presentation will address what the current regulations are and their effectiveness. I will additionally inform the audience about recent testing done by PRCI to evaluate the effectiveness of post installation coating inspection. To further the understanding we will review the newest guidance being supplied by PRCI and the upcoming changes to the regulations that are being put forth by PHMSA. The objective of this presentation is to educate pipeline owners contractors and coating applicators about the changes that have arisen in the past few years with regard to pipeline coating protection in these very sensitive environments so that we can better protect the community from incidents similar to what we saw in San Bruno or the leaks we've recently seen under The Great Lakes.
Painting Contractors generate more business and provide exceptional customer service by training themselves and the people who work for them to employ some easy to implement performance standards that get outstanding results.
Crude oils with a total acid number (TAN) higher than 0.5 are highly corrosive at temperatures between 400 and 700°F typical to atmospheric and vacuum distillations of oil refineries. This destructive effect of naphthenic acids (NAP) is enhanced by the presence of hydrogen sulfide generated in thermal decomposition of sulfur compounds also contained in crude oils. The efforts of mitigating the acidic crudes corrosive effects include blending such oils with crudes of lower acids content neutralization or removal of naphthenic acids from oils and the use of corrosion inhibitors. Most commonly used inhibitors for mitigating the NAP corrosion are based on organic polysulfides or on phosphate esters. Two phosphate esters corrosion inhibitors were evaluated in laboratory experiments using a specific testing procedure – “pretreatment - challenge”. This experimental method evaluates the naphthenic corrosive effects at high temperature on scales formed from crude factions on metal surfaces. Adding the inhibitors to the crude fractions improved the protective properties of scales formed under such conditions. The corrosive effect of naphthenic acid was evaluated by sample weight loss. The scales formed on these samples were investigated using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) coupled with energy dispersive spectroscopy (EDS).Keywords: phosphate esters corrosion inhibitors naphthenic acids high temperature
Silicon is an important element of our Planet’s crust, which is transferred into water streams through dissolution.1 Hence, it is usually found as water-soluble silicate or colloidal silica in natural surface waters (sea, rivers, lakes), or underground waters. When such water is used for industrial purposes (eg. industrial cooling), silicate can enter the operating system and can pose a threat to its proper operation. The main reason is the solubility of amorphous silica, a product of the silicate polycondensation process.