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Picture for Extended Connectivity of Zinc Pigments to Provide Enhanced Galvanic Coupling by Partial Replacement with Nanoparticles
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Extended Connectivity of Zinc Pigments to Provide Enhanced Galvanic Coupling by Partial Replacement with Nanoparticles

Product Number: 51319-13470-SG
Author: Saiada Fuadi Fancy
Publication Date: 2019
$20.00

Coatings are widely used to mitigate corrosion of highway steel bridges in aggressive exposure environments. Zinc-rich-primer three-coat (ZRP) systems have been used since the 1980’s. However coating failure of ZRP has been identified within 15 years of application well short of typical 75 year bridge design service life. Most of the reported coating failure included corrosion undercutting blistering and delamination. Partial replacement of zinc pigments with nanoparticles in ZRP coating systems have been shown to provide beneficial physical chemical and mechanical properties. These enhanced qualities may provide enhanced performance to mitigate premature coating failure. Earlier research showed that the nanoparticle enriched primer provided comparable corrosion resistance in aggressive environments as conventional three-coat systems. Nonetheless coating performance can be compromised by inappropriate surface preparation before coating application. Exposure to high humidity and surface contaminants (hygroscopic salt) as well as noncompliance to proper anchor profile requirements can initiate coating failure. The purpose of this study was to evaluate the effect of surface preparation with varying surface contaminants on the corrosion performance of a nanoparticle enriched zinc rich epoxy coating (NPE-ZRP) system. Adverse environmental condition exposure to different level of humidity (5% 75% and 100% RH) water immersion and salt contamination were incorporated before the coating application. After adverse exposure NPE-ZRP coating and a traditional ZRP coating (as a reference) were applied over the coupons. Cyclic testing in alternate wet/dry exposure was done for ~5 months. Coating and corrosion behavior was analyzed during the wet exposure of the cyclic testing by Open Circuit Potential (OPC) Linear Polarization Resistance (LPR) and electrochemical impedance spectroscopy (EIS). Physical parameters such as changes in coating thickness pull-off strength and cross-sectional micro-graphic analysis were also assessed to elucidate the extent of coating degradation.

Picture for Extension of Cathodic Protection Effect to Steel Piles At Tidal and Splash Zone
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Extension of Cathodic Protection Effect to Steel Piles At Tidal and Splash Zone

Product Number: 51314-3627-SG
ISBN: 3627 2014 CP
Author: Mohamed Khalil
Publication Date: 2014
$0.00