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A comprehensive corrosion investigation of a pipeline made of UNS N04400. Samples of the failed pipeline were obtained for investigation. The study concludes that the failure can be attributed to acidic corrosion that formed inside the pipeline.
Nickel-based alloy have an excellent corrosion resistance and good mechanical properties. The nickel-copper alloys (UNS(1) N04400) are used for broad of applications in an equally broad range of industries including chemical and petrochemical processing and oil and gas extraction. This paper present a comprehensive corrosion investigation of benzene condenser pipeline made of UNS N04400 at one of Saudi Basic Industries Corporation affiliates. Samples of the failed pipeline were obtained for analytical investigation. Metallographic examination was performed to evaluate microstructure of the failed pipe. The chemistry of a deposit collected from the pipe was analyzed by X-ray fluorescence (XRF) and carbon/ sulfur (C/S) analyzer. Scanning electron microscopy (SEM) coupled with energy dispersive spectroscopy was used to study the corrosion damage morphology and the chemical composition of the deposit at the leak points. The study concludes that the pipe failure attributed to acidic corrosion that form inside the pipeline.
Key words: Acidic corrosion, Nickel alloy, Benzene pipeline.
In the present study, detailed microstructure of the crack-tip region of a failed tube was examined using SEM, TEM and EBSD to clarify the relaxation crack mechanism. Details of the microstructural findings and a proposed mechanism of stress relief cracking will be discussed.
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Corrosion behavior of native naphthenic acids in two VGO fractions are compared with white oil solutions of the acids isolated from them by solid phase extraction (SPE). Tests are per the in-house “pretreatment-challenge” protocol on carbon steel and 5Cr steel samples.
A polyethylene unit experienced a gas leak within a high pressure tube and shell heat exchanger. Failure analysis revealed that the tube wall loss was beneath residual deposits. Preventative measures and improvements in inspection & cleaning procedures are discussed.