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Effect of CO in Stress Corrosion Cracking of Carbon Steel Pipelines in CCS Environments

Carbon monoxide (CO) is one of various possible impurities in carbon capture and storage (CCS) streams. As a by-product of the methane reforming process to produce blue hydrogen, CO is combusted and converted to carbon dioxide (CO2) and transported in pipelines. However, a trace amount of CO in the presence of oxygen (O2) and water can cause stress corrosion cracking (SCC) in carbon steel pipelines. This paper assesses the SCC risk of carbon steels induced by CO at different concentrations with or without O2 in lab simulated dense phase CO2 environments. Electrochemical measurements were also conducted to reveal the pseudo-passive behavior of carbon steels in different CO/O2/CO2 systems, and to help understand the resultant SCC behaviors.
Product Number: 51324-20647-SG
Author: Gaoxiang (Garret) Wu; Jose Rafael Vera; Ken Evans; Chong Li; William Kovacs
Publication Date: 2024
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