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Picture for Effect of Concrete Moisture on Macrocell Development in Repair of Reinforced Concrete Substructure with UHPC
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Effect of Concrete Moisture on Macrocell Development in Repair of Reinforced Concrete Substructure with UHPC

Product Number: 51319-13474-SG
Author: Mahsa Farzad
Publication Date: 2019
$20.00

Ultra-high-performance concrete (UHPC) has been introduced for reinforced concrete structures due to its enhanced mechanical performance including high compressive strengths and tensile compacity. In certain applications such as at closure joints connections and concrete repairs reinforcing steel may be embedded in dissimilar concrete elements partially incorporating the UHPC. Superficially UHPC can be considered to provide enhanced corrosion durability in marine environments due to its low permeability which would mitigate chloride-induced corrosion of rebar in the bulk material. However the localized galvanic effects of steel in dissimilar concrete in aggressive environments can be important. For example steel embedded in the concrete perimeter of repair patches can undergo premature corrosion failure after repair due to the halo effect. This research exploring the corrosion durability of steel embedded in dissimilar concretes incorporating UHPC examines the extent to which enhanced chloride transport may occur at the cold joint. The effectiveness of the bond at the concrete interface (with various levels of moisture availability at the time of UHPC repair) to minimize chloride penetration was examined. To this effect the substrate concrete was conditioned to moisture content (5% 75% 100% RH and wet) prior to UHPC repair concrete casting. Chloride penetration was accelerated by an impressed current and chloride content was assessed by concrete sampling at the cold joint as well as in the bulk concrete and potentiometric titrations.

Picture for Effect of corrosion products evolution/transformation on the localised/pitting corrosion behaviour of carbon steel in sour environment
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Effect of corrosion products evolution/transformation on the localised/pitting corrosion behaviour of carbon steel in sour environment

Product Number: 51319-12943-SG
Author: Frederick Pessu
Publication Date: 2019
$20.00

Carbon steel remain the most commonly used material in most oilfield applications. The susceptibility of carbon steel to various forms of corrosion is one of the major drawbacks to its remarkable economic and metallurgical advantages. Localized and/or pitting corrosion carbon steel used in oilfields is one aspect of its limitation that is very common and yet most unpredictable and difficult to mitigate against. The nature of the environment is also a key contributor to the evolution of localized and/or pitting corrosion especially in complex oilfield environment containing both H2S CO2 and other acid gases. The presence of H2S in a corrosion environment often introduces some complexities to the localized and/or pitting corrosion behaviour of exposed carbon steel materials. As a protection against uniform corrosion iron sulphide has been shown to form and has received much attention in the scientific literature. The evolution of iron sulphides (stoichiometric and non-stoichiometric) during the corrosion process of carbon steel is still not fully understood. This makes the already difficult challenge of predicting pitting/localized corrosion of carbon steel more complex and challenging especially since the electronic (and so conducting properties of iron sulphides) can mean that anodic/cathodic reactions can be supported on what are corrosion products or deposits on the corroding surface. This work focuses on understanding FeS formation evolution; dissolution and/or transformation using a combination of different electrochemical responses such as Linear and Tafel Polarization combined with post-experiment surface analysis such as XRD and SEM. It builds on and complements the large literature in this area. The study is carried out in 3.5 wt. % NaCl solution saturated with two different sour corrosion systems; H2S-CO2 and H2S-N2 at 80°C and for up to 21 days. The relationship between the processes of FeS formation evolution; dissolution and/or transformation and the evolution of localized and/pitting corrosion is also established. Pitting and/localized corrosion characterization is achieved using 3D surface profilometry which allows characterisation of discrete pit parameters such as depth diameter etc.

	Picture for Effect of Curing Time on the Performance of Novolac Internal Tank Coatings - a Realistic Assessment Using Laboratory Testing
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Effect of Curing Time on the Performance of Novolac Internal Tank Coatings - a Realistic Assessment Using Laboratory Testing

Product Number: 51324-20588-SG
Author: Amal Al-Borno; Moavin Islam; A. Al Hashem; Hasan Sabri
Publication Date: 2024
$40.00
Novolac coating systems are widely used for internal applications in tanks and pressure vessels due to their excellent corrosion resistance under aggressive conditions, their availability, and ease of application. Typically, these coatings require a curing time before putting the coating into service is typically around 7-8 days at (at 20-25o C). During the vessel shutdown, the production schedule sometimes demands compromising the curing process of the lining. This puts a time constraint on the end-user in terms of coating project duration. In response to this challenge, a major oil producing company was interested in finding out if shorter curing times would be suitable to reduce the downtime. The main objective of this study was to conduct a detailed laboratory investigation on the effect of different curing times on the coating performance of four Novolac systems selected from three different manufacturers. The assessment of coating curing involved a series of tests, including Differential Scanning Calorimetry (DSC) and Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR) analyses, shore-D Hardness, X-cut adhesion, and pull-off adhesion tests. Additionally, standard laboratory coating performance tests were carried out, consisting of water immersion, cathodic disbondment, autoclave in multi-phase environments at elevated pressure and temperature, as well as atlas cell (cold-wall effect) tests. The investigation results demonstrated that even though the coatings were not fully cured, all four coating systems showed acceptable laboratory performance, after just 1 day of curing. This implies that these coatings may be put into service much earlier than the specified curing period of manufacturer which would significantly reduce the project downtime during maintenance. Subsequent field test results (not reported here) confirmed the laboratory findings.
Picture for Effect of Cyclic Torquing on the Corrosion Resistance and Nut Factor Consistency of Coated High- Strength Steel Bolting
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Effect of Cyclic Torquing on the Corrosion Resistance and Nut Factor Consistency of Coated High- Strength Steel Bolting

Product Number: 51319-13268-SG
Author: Omar Rosas-Camacho
Publication Date: 2019
$20.00

Almost every piece of equipment and machinery in the Oil and Gas industry requires the use of bolted joints due to numerous advantages that they offer regarding productivity and maintenance however these advantages vanish by inadequate materials selection and installation procedures. Most anti-corrosion coatings applied to bolts do not offer a consistent tightening and they are affected by torqueing during assembly; the nut factor relates the bolt’s installation torque to the tension required to tighten the bolt maintaining a consistent nut factor would solve problems such as over-torquing and corrosion resulting from the coatings peeling-off which may lead to leaking from the joint and even to joint failure. Organic coatings have historically suffered from flaking and peeling when torqued hence metallic coatings such as Ni-Co electroplating may offer a more reliable performance.In order to obtain experimental data comparing the behavior of coatings used in bolted joints simulating service conditions cyclic torquing (up to 5 cycles) was applied to fasteners with different coatings and the nut factor and corrosion resistance was evaluated. The tested samples were B7M ASTM A193/A193M bolts and 2HM ASTM A194/A194M nuts with the following coating conditions: 1) No coating 2) Ni-Co Electroplating 3) zinc undercoat with PTFE topcoat and 4) TSA / PTFE. All samples were tested with dry runs (no lubricant) and two different commercial lubricants. A Skidmore-Wilhelm load cell was used to apply the cyclic torquing and to calculate the nut factor on each cycle. Corrosion tests were performed before and after torquing following ASTM G59 standard and environmental exposure following ASTM B368 standard to evaluate the materials corrosion resistance without torque. Ni-Co electroplating showed a better performance compared to the other tested coatings it offered the highest nut factor consistency and the lowest corrosion rate after the cyclic torqueing and after environmental exposure.The main impact of this work is providing consistent and reliable test data about nut factor and corrosion resistance of coatings; this data can be used to compare available coated fasteners for selection of the best solution for bolting in oilfield and industrial application. Ni-Co electroplating is featured as a coating that provides corrosion resistance and nut factor consistency regardless the number of assembly/disassembly cycles it is proposed as a solution to avoid joint leaking and likely catastrophic failures.