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This paper will present both laboratory and field trial results as evaluated with ASTM D610 for Zn-Ni nanolaminated and comparative coated fasteners and discuss how utilizing ASTM D610 helps to ensure objective, consistent red rust measurements.
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The corrosion of zirconium-based alloys is a service life-limiting factor in fuel rod performance. Mechanistic understanding of the corrosion process under reactor irradiation conditions still alludes to the nuclear industry. Pre-transition corrosion behavior of Zircaloy-4 has been reported to show a minimal effect from the irradiation environment, and the in-reactor corrosion kinetics is athermal and similar to the ex-situ autoclave corrosion exposure. However, the post-transition in-reactor corrosion kinetics depends on temperature and neutron flux. As discussed by Kammenzind et al. in Ref., the long-term post-transition corrosion rates of Zircaloy-4 are significantly accelerated in a PWR radiation environment over that observed with non-irradiated specimens in an autoclave environment.