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96130 SYNERGISTIC INHIBITORS FOR DILUTE HIGH-LEVEL RADIOACTIVE WASTE

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Product Number: 51300-96130-SG
ISBN: 96130 1996 CP
Author: Bruce J. Wiersma, Philip E. Zapp
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Cyclic potentiodynamic polarization scans were conducted to determined the effectiveness of various combinations of anodic inhibitors in the prevention of pitting in carbon steel exposed to dilute radioactive waste. Chromate, molybdate, and phosphate were investigated as replacements for nitrite, whose effective concentrations are incompatible with the waste vitrification process. The polarization scans were performed in non-radioactive waste simulants. Their results showed that acceptable combinations of phosphate with chromate and phosphate with molybdate effectively prevented pitting corrosion. Chromate with molybdate could not replace nitrite. Kcvwords: Carbon steel, pitting, cyclic potcntiodynamic polarization, nitrite, molybdate, chromate
Cyclic potentiodynamic polarization scans were conducted to determined the effectiveness of various combinations of anodic inhibitors in the prevention of pitting in carbon steel exposed to dilute radioactive waste. Chromate, molybdate, and phosphate were investigated as replacements for nitrite, whose effective concentrations are incompatible with the waste vitrification process. The polarization scans were performed in non-radioactive waste simulants. Their results showed that acceptable combinations of phosphate with chromate and phosphate with molybdate effectively prevented pitting corrosion. Chromate with molybdate could not replace nitrite. Kcvwords: Carbon steel, pitting, cyclic potcntiodynamic polarization, nitrite, molybdate, chromate
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