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96121 NUMERICAL SIMULATION OF CREVICE CORROSION OF TITANIUM: EFFECT OF THE BOLD SURFACE

Product Number: 51300-96121-SG
ISBN: 96121 1996 CP
Author: R.W. Evitts, M.K. Watson, J. Postlethwaite
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A rigorous crevice corrosion model has been developed that accounts for the bold metal surfaces exterior to the crevice. The model predicts the time change in concentration of all specified chemical species in the crevice and bulk solution, and has the ability to predict active corrosion. It is applied to the crevice corrosion of a small titanium crevice in both oxygenated and anaerobic sodium chloride solutions. The numericat predictions confirm that oxygen is the driving force for crevice corrosion. During the simulations where oxygen is initially present in both the crevice and bulk solution an acidic chloride solution is developed; this is the precursor required for crevice corrosion. The anaerobic case displays no tendency to form such a solution. It is also confirmed that those areas in the crevice that are deoxygenated become anodic and the bold metal surface becomes cathodic. As expected, active corrosion is not attained as the simulations are based on electrochemical and chemical parameters at 25°C. Keywords: crevice corrosion, titanium, mathematical modelling, oxygen, chloride
A rigorous crevice corrosion model has been developed that accounts for the bold metal surfaces exterior to the crevice. The model predicts the time change in concentration of all specified chemical species in the crevice and bulk solution, and has the ability to predict active corrosion. It is applied to the crevice corrosion of a small titanium crevice in both oxygenated and anaerobic sodium chloride solutions. The numericat predictions confirm that oxygen is the driving force for crevice corrosion. During the simulations where oxygen is initially present in both the crevice and bulk solution an acidic chloride solution is developed; this is the precursor required for crevice corrosion. The anaerobic case displays no tendency to form such a solution. It is also confirmed that those areas in the crevice that are deoxygenated become anodic and the bold metal surface becomes cathodic. As expected, active corrosion is not attained as the simulations are based on electrochemical and chemical parameters at 25°C. Keywords: crevice corrosion, titanium, mathematical modelling, oxygen, chloride
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