Parts from stainless steels owe their chemical resistance to the functional properties of their surfaces.
They are responsible for the corrosion resistance and also for other properties like adhesion of substrates
or ease to clean. The passive layer forms the phase boundary between metal and environment. It is
formed either spontaneously during the fabrication or can be produced in an accelerated way by specific
chemical treatments. The quality of the passive film is dependant of the alloying content of the metal,
but also largely influenced by other factors like fabrication processes, surface topography and type of
mechanical and chemical surface treatment. The passive layer is also a kind of living system whose
properties and stability is largely influenced by the environment where it is used in. So far, there are no
methods to characterize these functional surface properties in a generally applicable way. Combination
of special electrochemical techniques in combination with measurements of the surface energy have
shown to be useful tools. This permits to characterize and to classify the functional properties of
surfaces which have been produced by mechanical and special chemical and electrochemical treatments.