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07601 Effect of Alloying Elements on the Oxidation Kinetics of Zirconium Based Alloys Under High Pressure Steam

Picture for 07601 Effect of Alloying Elements on the Oxidation Kinetics of Zirconium Based Alloys Under High Pre
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Product Number: 51300-07601-SG
ISBN: 07601 2007 CP
Author: Yacoub Dali, Marc Tupin, Philippe Bossis, Michele Pijolat, and Francoise Valdivieso
Publication Date: 2007
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The corrosion behaviour of different zirconium based alloys has been studied at various steam pressures. The objectives of this work were to understand and explain the effect of alloying elements and steam pressure on the corrosion resistance. The precipitate free alloys, like “pure” Zr and the binary alloy Zr-1.15%Sn, show catastrophic corrosion rates at high pressure while their behaviour at low steam pressure is similar to that of Zy4, which is almost insensitive to pressure change. As already observed, the corrosion rate of Zr-xNb alloys depends on the niobium concentration in the alloy. All these experimental facts are discussed from a kinetic point of view.
The corrosion behaviour of different zirconium based alloys has been studied at various steam pressures. The objectives of this work were to understand and explain the effect of alloying elements and steam pressure on the corrosion resistance. The precipitate free alloys, like “pure” Zr and the binary alloy Zr-1.15%Sn, show catastrophic corrosion rates at high pressure while their behaviour at low steam pressure is similar to that of Zy4, which is almost insensitive to pressure change. As already observed, the corrosion rate of Zr-xNb alloys depends on the niobium concentration in the alloy. All these experimental facts are discussed from a kinetic point of view.
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