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07617 “I PUT IT IN, BUT WHERE DOES IT GO?” – THE FATE OF CORROSION INHIBITORS IN MULTIPHASE SYSTEMS

Picture for 07617 “I PUT IT IN, BUT WHERE DOES IT GO?” – THE FATE OF CORROSION INHIBITORS IN MULTIPHASE SYSTEMS
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Product Number: 51300-07617-SG
ISBN: 07617 2007 CP
Author: David I. Horsup, J. Caleb Clark, Bernard P. Binks, Paul D.I. Fletcher, and Jake T. Hicks
Publication Date: 2007
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The work reported in this paper addresses some of the principal properties of corrosion inhibitors and how these impact the ultimate fate of the inhibitor in a production system. Specifically, the partitioning behavior of corrosion inhibitors is discussed and how this is affected by changes in inhibitor structure, temperature, brine salinity and oil type. Competitive, parasitic adsorption onto unwanted surfaces is discussed. The affinity of various corrosion inhibitors for sand, iron sulfide, barium sulfate, iron carbonate and emulsion drop surfaces is presented. Additionally, the ability for corrosion inhibitors to stabilize both oil-in water and water-in-oil emulsions is discussed. Phase inversion of the emulsion is demonstrated as production variables change.
The work reported in this paper addresses some of the principal properties of corrosion inhibitors and how these impact the ultimate fate of the inhibitor in a production system. Specifically, the partitioning behavior of corrosion inhibitors is discussed and how this is affected by changes in inhibitor structure, temperature, brine salinity and oil type. Competitive, parasitic adsorption onto unwanted surfaces is discussed. The affinity of various corrosion inhibitors for sand, iron sulfide, barium sulfate, iron carbonate and emulsion drop surfaces is presented. Additionally, the ability for corrosion inhibitors to stabilize both oil-in water and water-in-oil emulsions is discussed. Phase inversion of the emulsion is demonstrated as production variables change.
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