The formation of struvite scale formation was investigated in synthetic wastewater, 25°C, pH
8.50 both in the absence and in the presence of heavy metals cadmium(Cd), copper (Cu) and
lead (Pb). The concentrations of the tested metals was in the range between 1-10 µM to avoid
metal hydroxide precipitation. The investigation was done at conditions of constant
supersaturation. Synthetic wastewater, aqueous solutions with composition similar to typical
municipal wastewater was used as a matrix for the preparation of the supersaturated solutions.
The kinetics of struvite precipitation was affected by the presence of the metal ions tested at
concentrations as low as 1 µM. The presence of cadmium resulted in narrower stability
domain for the struvite system, while increasing concentrations in solution resulted in shorter
induction times. The rates of precipitation were also faster up to 5µM, past which they started
reducing. The presence of copper resulted in acceleration at low concentrations (1 µM) and
inhibition at higher concentrations (>4 µM). The presence of lead showed a more consistent
behavior, resulting in increasingly longer induction times and lower rates of precipitation with
increasing metal concentration. It should be noted that all three metals investigated were
taken up by the solid either by electrostatic interactions or by other mechanisms (e.g., surface
complexation or surface precipitation). The morphology was not affected by the presence of
the metals examined.