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This presentation summarizes the development and expansion of a comprehensive information system for corrosion of metals and alloys in high temperature gases. New insights in analysis of thermochemical data for the Fe-Ni-Cr-Co-C-O-S-N system are being compiled. Corrosion mechanisms emphasized are oxidation, sulfidation, sulfidation/oxidation, and carburization.
A new wrought alloy has been developed for use as furnace tubes in ethylene pyrolysis plants. This alloy has an excellent carburization resistance due to uniform formation of protective Al2O3 oxide scale on the metal surface. Laboratory corrosion tests have been carried out to evaluate carburization resistance of the developed alloy.