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Picture for Applicability of 15%Cr and 17%Cr Martensite-Based Stainless Steel OCTG Materials for Seawater Injection Service
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Applicability of 15%Cr and 17%Cr Martensite-Based Stainless Steel OCTG Materials for Seawater Injection Service

Product Number: 51321-16310-SG
Author: Yasuhide Ishiguro/Yusuke Mizuno/Takashi Koga/Yuichi Kamo/Tsuyoshi Yoneyama
Publication Date: 2021
$20.00
Picture for Effect of Dissolved Oxygen on Carbon Steel Corrosion and Particulate Formation. Part 1: Rotating Cylinder Electrode Experiments
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Effect of Dissolved Oxygen on Carbon Steel Corrosion and Particulate Formation. Part 1: Rotating Cylinder Electrode Experiments

Product Number: 51324-20718-SG
Author: K. J. Evans; J. Vera; C. Mendez
Publication Date: 2024
$40.00
The dissolved oxygen concentration (DOC) in seawater injection systems is typically maintained near 10 to 20 ppb. However, these systems can experience DOC excursions that temporarily rise into the 100 to 1000 ppb range. The use of carbon steel piping in some systems is known to result in elevated corrosion rates during upset periods in which DOC increases. However, the particles that are generated from corrosion products during upset conditions are not well characterized or understood. The importance of understanding corrosion-generated particles relates to the plugging of the injection lines, which can lead to costly work-overs of the injection well. The main objective of this work is to examine the impact of DOC excursions on steel corrosion and iron-based particulates that form as a result of corrosion. A rotating cylinder electrode (RCE) electrochemical setup was implemented in conjunction with a particle analyzer instrument to make these correlations in real-time under controlled hydrodynamic conditions. Dissolved oxygen and pH were also continuously monitored throughout the tests. All testing was performed in a seawater simulant brine at 32°C. The key findings from the testing can be summarized accordingly: (1) particle sizes in the 20 to 30 µm range tended to concentrate when the DOC was raised to 1000 ppb; (2) localized corrosion was able to develop on the steel electrodes due to breakdown of a semi-protective film that formed over time; (3) DOC excursions may lead to irreversible increases in the baseline corrosion rate after dissolved oxygen is reduced back to low levels (e.g., 20 ppb).
	Picture for Localized Corrosion Limit of Use of S13%Cr (UNS S41427) Connector in Converted Injection Treated Seawater Well
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Localized Corrosion Limit of Use of S13%Cr (UNS S41427) Connector in Converted Injection Treated Seawater Well

Product Number: 51324-20714-SG
Author: Nicolas Larché; Marianne Kleive; Charles Leballeur; Eva Malmanger
Publication Date: 2024
$40.00
Many systems can be converted and used for different applications not initially planned. This is the case for production wells, sometimes converted into water injection wells and for which the production tubing material selection is clearly not adapted for prolonged contact with natural seawater. Oxygen removal treatment must be applied but precise control is not obvious and excursions above zero or close-to-zero oxygen can occur. The production tubing material S13%Cr are known to be sensitive to dissolved oxygen excursions in seawater, but data from the literature cannot precisely help in defining the allowed limits of use. Exploring the possibility to convert a production well into a treated seawater injection well then requires a careful assessment of the corrosion resistance limits of the involved alloys. A series of corrosion tests in treated seawater were designed to assess the limits of use of fast connector made of alloy UNS S41427. The corrosion tests were performed both at laboratory scale and on full-scale fast connectors in a treated seawater flow loops simulating service conditions. For all the performed tests, maintaining the dissolved oxygen content (DOC) at 15 ppb and below never led to localized corrosion and has been considered as a safe condition in terms of corrosion risk for alloy S41427 at ambient temperature. It was found that prolonged dissolved oxygen content (DOC) above 30±10 ppb may lead to initial crevice corrosion after only 4 h of exposure. Globally, a very good correlation between the laboratory and the full-scale test results was found. The critical crevice potential for alloy S41427 was significantly affected by the cleaning process of the tested coupons, while the stop of the corrosion was always measured for potentials reached at DOC < 10 ppb. The proposed methodology, involving both laboratory and full-scale tests, allowed to precisely quantify the limits of use of UNS S41427 in treated injection well. It could be used for any other material and applications to help at designing adapted and reliable engineering diagrams for material selections.