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Low Cr (3 to 5%) bearing steels have been developed and used in CO2 environment as materials to meet "Fitness for Purpose". However, the SSC and SCC resistance of low Cr bearing steel have not been clarified. This paper presents the effect of carbon content, microstructure, and tempering temperature on the SSC and SCC resistance as well as CO2 corrosion resistance of low Cr steel (3%Cr steel).
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Analysis of corrosion of carbon steel in sour and sweet environments. Non-classical nature of localized pitting corrosion of carbon steel in sour and sweet environments explained. Description of a model to predict internal pitting corrosion of carbon steel under sour and sweet environments,
The current paper presents a study on corrosivity of produced water and make-up water on UNS G10180 carbon steel in simulated in-situ thermal operations.
Nitrogen-based model CI compounds with different functional groups and sulfur containing synergist molecules were selected for mechanistic study. The oil-water partitioning behavior and corrosion performance of these model compounds were investigated and correlated to their chemical structures in a variety of sweet corrosion environments.
Corrosion of pipelines made of carbon steel and exposed to wet hydrocarbons containing CO2 and H2S is a common but serious problem encountered in petroleum industry and its occurrence causes enormousexpense due to production downtime, accidental injuries, and replacement costs. Control and prevent corrosion using chemical treatment (e.g. corrosion inhibitor injection) is one of the most cost-effective solutions and commonly practiced methods to prevent corrosion failures in pipelines in oil and gas industry. Generally speaking, the active corrosion inhibitor (CI) components in commercial CI packages are usually organic, nitrogen-based surfactants such as amines, imidazoline and its derivatives. Due to the amphiphilic nature of surfactants, a good fraction of the injected CI will inevitably go into the oil phase through partitioning and to the oil/water interface.
Sweet corrosion of Oil Country Tubular Goods (OCTG) is a major concern in the oil and gas industry. This paper will present the experimental results and discuss the effects of temperature and Chromium content in OCTG on corrosion rate.
Corrosion and corrosion inhibitor qualification testing has been the subject of many publications over the years, with various guidelines and in-house protocols produced. This has led to a rather large set of test approaches for the qualification of corrosion inhibitors (CIs) for application in oil and gas production facilities.
For challenging conditions, including severe downhole conditions, final testing is often performed via specialized autoclaves or high-pressure flow loops to allow tests to be conducted under conditions as close to those pertaining in the field: T, P, pCO2 and pH2S (or more realistically, fugacity of CO2 and H2S), and as close as can be achieved to the field hydrodynamics.
The standard type of chemicals long used as oilfield corrosion inhibitors are so-called filmforming molecules carrying a positive net charge. More specifically, these additives belong to e.g. the classes fatty amines, alkoxylated fatty amines, amidoamines, imidazolines, pyridinium quats, and quarternary ammonium compounds like alkyl benzyl quats. Anionic molecules, predominantly phosphate esters, may sometimes also be used as stand-alone inhibitors or as enhancers in formulations with a base inhibitor of the abovementioned type.
Carbon steels and low alloy steels are the workhorse of several industries where properties such as strength, fracture toughness and weldability play a key role. In addition to these properties, carbon steels are also the most cost effective materials is several applications. Of particular interest is the API 5L X65 which is widely used in oil and gas exploration, production and transportation service.