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The electrical conductivity of the electrolyte is one of the key parameters in the electromechanics of corrosion. Highly conductive electrolytes will permit more current and increase corrosion rates. Conversely, resistive electrolytes will enable less current to flow until the necessary conditions for corrosion are no longer satisfied or slowed.
Newly developed 13%Cr steels with 0.010-0.18%C, 4%Ni, and 1%Mo show excellent corrosion resistance in severe sweet environments, such as temperature of 300F (150C), 20%NaCi, and 560psi (3.85MPa) PCO2, which the conventional API 5CT 13%Cr (0.15-0.22%c) can not withstand.
In recent years, unexpected failure caused by sulfidation corrosion have increased presumably because many refineries diversify the crude oils to process them. Crude oils contain corrosive species such as sulfides, nitrides, chlorides, organic acids and chemical additives. In these corrosive species, sulfides in the fluids cause sulfidation corrosion operating at temperature above approximately 260 °C1.
The control of multiphase flow corrosion in oil and gas industry is one of the biggest challenging tasks. Since the 1990s, several organizations have established and operated large-scale flow loops to simulate and reproduce the field service environment of oil and gas pipelines. Based on comparison and investigation of the above loops, a new and advanced system, including several four inches internal diameter loops for studying corrosion under multiphase flows, was successfully built by us. By using this system, multiphase flows with various combinations of gas, water, oil and sand can be realized at the highest temperature of 140 oC and the highest pressure of 10 Mpa. Moreover, some loops in this system can adjust pipeline at different angels from 0 to 90°, which allow horizontal/vertical/sloping conditions to be simulated in laboratory. Many advanced measuring and monitoring technologies, such as Particle Imaging Velocimetry (PIV), high speed video camera and LPR/ER probe, are employed for simultaneously recording flow events and corrosion rates. An inhouse plane three-electrode probe is employed for conducting in situ electrochemical measurements. Such technologies would allow deep researching of corrosion behaviors and mechanisms in multiphase flow environments. Moreover, a new software based on Fluent and the existing multiphase corrosion models was developed to realize the numerical simulation of multiphase flow in loop.
The concrete biological shields (CBSs) of light water reactors are affected by neutron and gamma irradiation at high radiation doses, resulting in the degradation of the concrete’s material properties. Several studies in the literature focused on evaluating both the expansion of aggregate-forming minerals and the resulting loss of mechanical properties. Modeling efforts have been carried out to predict theradiation-induced volumetric expansion (RIVE) and damage using different numerical methods such as the finite element method or fast-Fourier transform (FFT).
Drag Reducing Agents (DRA) usage in liquid petroleum pipelines has increased over the past few decades, as they improve the mechanical efficiency of flow systems, but their potential impact on different aspects affecting corrosion management has not been fully evaluated. For example: DRA may a) decrease mass transfer and velocity near-wall, reducing flow induced localized corrosion or erosion-corrosion; b) introduce changes in the oil/water interface, affecting water-in-oil stratification and water-oil phase inversion point; c) affect the function of corrosion inhibitors by adsorbing to surfaces or direct chemical interaction.
The potential effect on water accumulation was not included in the model developed for the Pipeline Research Council International, Inc (PRCI) or in other models that are typically used6 for the indirect inspection step of the Liquid Petroleum Internal Corrosion Direct Assessment methodology (LP-ICDA).
Assessing the corrosion degradation of aboveground tank bottom plates is a critical challenge for the industry. Internal inspections are a useful way of assessing the integrity of assets but might severely impact normal plant operation. In 2006, Chang et al. conducted a study on storage tank accidents and concluded that 74% of reported accidents occurred in petrochemical refineries, and 85% of them had caused fire and explosions.