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Picture for Corrosion of Carbon Steel in Supercritical CO2/H2S and Its Mitigation Using Coatings
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Corrosion of Carbon Steel in Supercritical CO2/H2S and Its Mitigation Using Coatings

Product Number: 51319-12768-SG
Author: Shiladitya Paul
Publication Date: 2019
$20.00

Carbon steels are widely used in the oil and gas exploration and production service. These steels are prone to corrosion in CO2 and cracking in H2S. The propensity to cracking increases when high strength grades are employed. The use of corrosion resistant alloys incurs costs and only when these costs are justified can such materials be used in industrial service. If these materials can be coated by an industrial method onto carbon steel then their industrial uptake can be increased. To understand the behaviour of CRA coatings on steel several carbon steel coupons were sprayed using high velocity oxy-fuel (HVOF). Carbon steel specimens with and without CRA coatings were then tested in de-aerated 1000mg/L Cl- solution for 30 days bubbled with 10MPa CO2 at 40°C. In some cases tests were also carried out in supercritical CO2 containing 0.1MPa H2S. Microstructural characterization revealed that the carbon steel formed different scales siderite in pure 10MPa CO2 and mackinawite in CO2 containing 0.1MPa H2S. CRA coatings protected the steel substrate from CO2 corrosion when undamaged and no scale was seen.It was concluded that thermally sprayed CRA coatings can provide a cost-effective corrosion mitigation method for infrastructure likely to be in contact with wet supercritical CO2at 40°C. The scales formed on the steel somewhat protected it from further corrosion in 10 MPa CO2. However it was evident that care must be taken to ensure that the thermally sprayed CRA layer does not have any through porosity or defect; else such coatings may accelerate corrosion of the underlying steel substrate due to galvanic interactions.

Picture for Corrosion of Copper Coils in Computer Air Handlers
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Corrosion of Copper Coils in Computer Air Handlers

Product Number: 51315-5963-SG
ISBN: 5963 2015 CP
Author: Todd Mintz
Publication Date: 2015
$0.00
Picture for Corrosion of Ferrous Alloys by Organic Compounds in Simulated Bio-Oils
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Corrosion of Ferrous Alloys by Organic Compounds in Simulated Bio-Oils

Product Number: 51319-12895-SG
Author: Jiheon Jun
Publication Date: 2019
$20.00

Biomass-derived oils have gained considerable interest as a renewable energy source to decrease use of fossil fuels. These bio-oils often contain organic compounds that can be corrosive to ferrous alloys used for pipelines and storage tanks. It is therefore important to assess corrosivity of organic compounds in bio-oils and identify ferrous alloys with sufficient corrosion resistance. In this work 16 organic compounds selected on the basis of analyses of commercial bio-oils were used to formulate simulated bio-oil solutions that contained single or two organic species with total concentrations up to 0.2 molal. Type 410 430 316L and 201 stainless steels as well as 2.25Cr-1Mo steel were evaluated using Electrochemical Impedance Spectroscopy (EIS) to assess their corrosion resistance. For type 410 0.1 molal lactobionic acid was considerably more corrosive than other organic species. Catechol and formic acid were also highly corrosive to type 410 and the mixtures of the two were used to test the other steels. Type 201 was more corrosion-resistant than type 410 in formic acid and catechol + formic acid solutions. However in catechol solution the corrosion resistance of type 201 and 410 was quite similar. The 2.25Cr-1Mo steel exhibited the least corrosion-resistance in these solutions as expected given its low alloy content. Currently EIS-based corrosivity measurements are being conducted for type 316L. The outcome of this work will provide guidance on the selection of appropriate structural materials for bio-oil production transport and processing systems. This research was sponsored by the U.S. Department of Energy Bioenergy Technologies Office.

Picture for Corrosion Of Open-Cell Aluminum Foams In Natural Seawater
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Corrosion Of Open-Cell Aluminum Foams In Natural Seawater

Product Number: 51321-16926-SG
Author: Alessandro Pereyra; Rogine Gomez; Ho Lun Chan; Vilupanur Ravi
Publication Date: 2021
$20.00
Picture for Corrosion Of Reactor Alloys Under Simulated Partially Thermal Cracking Of Oilsands Bitumen
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Corrosion Of Reactor Alloys Under Simulated Partially Thermal Cracking Of Oilsands Bitumen

Product Number: 51321-16575-SG
Author: Xue Han/ Yimin Zeng
Publication Date: 2021
$20.00