Menu
Search
Filters
Close
Menu

Save 20% on select titles with code HIDDEN24 - Shop The Sale Now

51318-10828-Modeling Mineral Scaling in Oil and Gas Environments up to Ultra High Pressures and Temperatures

Picture for Modeling Mineral Scaling in Oil and Gas Environments up to Ultra High Pressures and Temperatures
Available for download

To address the need to predict scaling at conditions ranging from ambient to extreme, a thermodynamic model has been developed to represent the solubility of scaling minerals at temperatures up to 300 °C and pressures up to 1,700 atmospheres.

Product Number: 51318-10828-SG
Author: M.M. Lencka, R.D. Springer, P. Wang and A. Anderko
Publication Date: 2018
Industry: Oil and Gas Production
$0.00
$20.00
$20.00

Mineral scale prediction is an important tool for effective scale management in oil and gas flow assurance.

Accurate prediction of scale formation is particularly challenging at high temperatures and pressures that are encountered as the industry develops progressively deeper and overpressured reservoirs. To address the need to predict scaling at conditions ranging from ambient to extreme, a comprehensive thermodynamic model has been developed. This model has been designed to represent the solubility of scaling minerals at temperatures up to 300 °C and pressures up to at least 1,700 atm. The model is based on the previously developed Mixed-Solvent Electrolyte (MSE) thermodynamic framework and relies on a detailed treatment of speciation in the liquid phase. It represents the standard-state properties of individual species using the Helgeson-Kirkham-Flowers equation of state and it predicts the species activity coefficients by accounting for long-range electrostatic, short-range ionic, and non-ionic interactions. The model has been parameterized to reproduce the solubility of sulfate, sulfide, and carbonate scales in water and in multicomponent brines ranging from dilute to highly saline (typically up to ~6 m Cl). The model accurately represents the effects of temperature, pressure and common salt components on the solubility of the minerals. Additionally, it takes into account the effect of metastability for scales that may occur in multiple crystalline forms. Application of the model to zinc sulfide, lead sulfide and calcium sulfate scales is analyzed in detail.

Key words: Scaling, flow assurance, thermodynamics, electrolyte solutions, solubility, speciation

Mineral scale prediction is an important tool for effective scale management in oil and gas flow assurance.

Accurate prediction of scale formation is particularly challenging at high temperatures and pressures that are encountered as the industry develops progressively deeper and overpressured reservoirs. To address the need to predict scaling at conditions ranging from ambient to extreme, a comprehensive thermodynamic model has been developed. This model has been designed to represent the solubility of scaling minerals at temperatures up to 300 °C and pressures up to at least 1,700 atm. The model is based on the previously developed Mixed-Solvent Electrolyte (MSE) thermodynamic framework and relies on a detailed treatment of speciation in the liquid phase. It represents the standard-state properties of individual species using the Helgeson-Kirkham-Flowers equation of state and it predicts the species activity coefficients by accounting for long-range electrostatic, short-range ionic, and non-ionic interactions. The model has been parameterized to reproduce the solubility of sulfate, sulfide, and carbonate scales in water and in multicomponent brines ranging from dilute to highly saline (typically up to ~6 m Cl). The model accurately represents the effects of temperature, pressure and common salt components on the solubility of the minerals. Additionally, it takes into account the effect of metastability for scales that may occur in multiple crystalline forms. Application of the model to zinc sulfide, lead sulfide and calcium sulfate scales is analyzed in detail.

Key words: Scaling, flow assurance, thermodynamics, electrolyte solutions, solubility, speciation

Product tags
Also Purchased
Picture for Effect of different parameters on the inhibition efficacy of decanethiol
Available for download

51318-10823-Effect of different parameters on the inhibition efficacy of decanethiol

Product Number: 51318-10823-SG
Author: Z. Belarbi / F. Farelas / D. Young / M. Singer / S. Nesic
Publication Date: 2018
$20.00

The overall objective of the present research is to investigate the effect of operating parameters on the inhibition efficacy of decanethiol in top of the line corrosion (TLC).
Picture for The Promise of a Holistic Digital Strategy for Corrosion and Integrity Management
Available for download

51318-10831-The Promise of a Holistic Digital Strategy for Corrosion and Integrity Management

Product Number: 51318-10831-SG
Author: Cecilie A. Haarseth / David A. Norman
Publication Date: 2018
$20.00

 An overview and possible methods to capture the full potential of digital technologies for corrosion and integrity management with a focus on upstream pipelines. Considering current industry offerings but also potential new technologies.
Picture for Technical evaluation of cold end-sizing and stress-relieving mill operations while preserving the SSC resistance of sour service OCTG pipes
Available for download

51318-10821-Technical evaluation of cold end-sizing and stress-relieving mill operations while preserving the SSC resistance of sour service OCTG pipes

Product Number: 51318-10821-SG
Author: John Fortaillier / Julien Millet / Florian Thébault
Publication Date: 2018
$20.00

How tensile properties behave after thermal stress-relieving with regards to the cold-forming history of the material and how this correlates to the SSC resistance of pipe-ends sampled.
Categories
Industry
Recently viewed
Popular tags
View all

Association for Materials Protection and Performance

© AMPP All Rights Reserved.
Membership Terms of Content Use
Contact Customer Support