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Enhanced Biocide Treatment Using D-tyrosine Against Desulfovibrio Vulgaris Corrosion of Carbon Steel

Biocides are used to control problematic microorganisms in the oil and gas industry. High doses of biocides cause environmental and operational problems. Therefore, using biocide enhancers to make biocides more effective is highly desirable. 2,2-dibromo-3-nitrilopropionamide (DBNPA) is a popular biocide because it is broad-spectrum, effective, kills microorganisms immediately upon addition, and it degrades rapidly. D-amino acids are natural chemicals that have been used in lab tests to enhance biocides to treat biofilms. In this work, D-tyrosine was used to enhance DBNPA against Desulfovibrio vulgaris biofilm on C1018 carbon steel. After 7 days of incubation, the weight loss of coupons without treatment chemicals in culture medium was found to be 3.1 ± 0.1 mg/cm2. With a treatment of 150 ppm (w/w) DBNPA, the weight loss was reduced to 1.9 ± 0.1 mg/cm2 accompanied by a 1-log reduction in the sessile cell count. The combination of 150 ppm DBNPA + 1 ppm D-tyrosine achieved an extra 3-log reduction in sessile cell counts and an additional 30% reduction in weight loss compared with 150 ppm treatment of only DBNPA. The combination also led to a smaller maximum pit depth. Linear polarization resistance (LPR), potentiodynamic polarization and electrochemical impedance spectrometry (EIS) tests corroborated the enhancement effects.  

Product Number: 51320-14527-SG
Author: Tuba Unsal, Di Wang, Tingyue Gu, Sith Kumseranee, Suchada Punpruk
Publication Date: 2020
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Development of a concentrated corrosion inhibitor compatible with produced water brine and scale inhibitor

Product Number: 51320-14668-SG
Author: Sathees Kesavan, John Samuel Selvaraj, Suresh Seethalakshmi, Yure Queiros, Andrade Gessie, Nicolas Scanarotti
Publication Date: 2020
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Oil and gas production field requirements to maintain asset integrity and scale control are very diverse. In an operator’s field in Latin America, the conditions across several wells required the co-injection of corrosion and scale inhibitors. The brine composition of these wells is challenging due to relatively high concentration of calcium ions as well as the presence of iron. The selected scale and corrosion inhibitors need to be compatible with brine and with each other without negatively impacting the absolute performance of the individual products. An additional practical challenge for product selection was imposed by the extreme remote location of the field requiring the product to perform at an optimal dosage without increased transportation and logistics costs.  

This paper describes the results from screening studies conducted with a series of corrosion inhibitor product formulations using different static and dynamic lab performance evaluation test methods. As the primary corrosion inhibitor actives are oil-soluble by nature, focus was given to formulating the product with an appropriate selection of solvents, such as methanol and isopropanol, and surfactants to achieve the desired compatibility with the brine and scale inhibitors. The final products were identified, and an optimal product dosage was arrived at based on tests conducted under typical and aggressive conditions representative of the field. However, due to the diversity of conditions and corrosion severity levels across multiple wells in this field, corrosion prediction simulations were run for unmonitored wells to estimate a baseline corrosion rate and build confidence in the recommended corrosion inhibitor product dosage. The validation of the prediction for monitored wells with ER probes will also be discussed in this study.  

Picture for Investigation of Acid Corrosion Inhibition Using N,N′-(1,4-phenylenebis(methyl))bis(N,N-dimethylalkan-1-aminium) Chloride Corrosion Inhibitors
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Investigation of Acid Corrosion Inhibition Using N,N′-(1,4-phenylenebis(methyl))bis(N,N-dimethylalkan-1-aminium) Chloride Corrosion Inhibitors

Product Number: 51320-14723-SG
Author: Norah Aljeaban, Nurudeen A. Odewunmi, Bader Alharbi, Mohammad A. Jafar Mazumde, Salem Balharth, Shaikh A. Ali
Publication Date: 2020
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The application of corrosion inhibitors (CI) to producing oil and gas field systems is one of the most common practices of corrosion control. Acid stimulation fluids such as hydrochloric acid (HCl) and organic acids has high calcite and dolomite dissolving power; however, pumping HCl downhole during acid stimulation process particularly at elevated temperatures can cause severe corrosion. Therefore, the addition of corrosion inhibitors is indispensable to protect the metal from corrosion. More inhibitors that are efficacious are still needed to provide better protection against the corrosion.
Two new bisquaternary ammonium salts; 1,4-Benzenedimethanaminium, N,N'-didodecyl-N,N,N',N'-tetramethyl-, dichloride (CI-1) and 1,4-Benzenedimethanaminium, N,N'-dihexadecyl-N,N,N',N'-tetramethyl-, dichloride (CI-2) as corrosion inhibitors were successfully synthesized, characterized and electrochemically evaluated for their corrosion inhibition efficiency in 1 M hydrochloric acid (HCl) solution on API 5L X60 low carbon steel. Potentiodynamic polarization measurement revealed mixed type inhibition mechanisms of the synthesized inhibitors. Inhibition efficiency of CI-1 increase with increase in concentration 2.0 to 20.0 ppm while CI-2 efficiency does not go beyond 2 ppm. Adsorption isotherm of CI-1 was found to deviate from Langmuir isotherm due to its interaction on low carbon steel and the interaction was approximated by Temkin isotherm. Analysis of the adsorption of CI-1 on API 5L X60 involve both physisorption and chemisorption.