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Electrochemical methods can be used more effectively if innovative experiments are designed and employed. This is especially true if a corrosion system to be tested involves inhibitors that could change the mechanism and pattern of corrosion in complex ways. This paper discusses corrosion inhibitor test design using several practical cases as examples. Particular attention is on difficult issues such as the simulation of localized corrosion phenomena and the influence of corrosion mechanism on inhibitor test results.
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Experiments to determine the critical pitting temperature of several alloys in calcium bromide solutions using the ASTM G150 electrochemical critical pitting test procedures. Similar experiments were also conducted in solutions containing equal concentrations (by weight) of chlorides and bromide.