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Cathodic Protection -Based Solutions For Corrosion Prevention Of “Green Aluminum” Alloys

In the recent years, the reduction of the environmental footprint of industrial processes is gaining momentum, targeting the carbon neutrality. This also involves Aluminum industry, in which the use of secondary (e.g. recycled) alloys is a possible solution in order to decrease the greenhouse gases (GHG) emissions. Indeed, raw materials produced starting from secondary Aluminum show GHG emission values up to one order of magnitude lower with respect to their primary equivalents.

Product Number: 51322-17823-SG
Author: Marco Bandiera, Arianna Pavesi, Alessandro Mancini, Bozhena Tsyupa, Andrea Bonfanti, Massimiliano Bestetti, Federico Bertasi
Publication Date: 2022
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The manuscript investigates the use of cathodic protection -based strategies (e.g. sacrificial anodes) to prevent corrosion phenomena of two green (e.g. recycled) 43200 and 46400 Aluminum alloys. These materials are selected due to their high concentration of alloying elements (e.g. Si, Cu, Fe) that renders them as a representative example of the typical composition of secondary Aluminums. Voltammetry and zero resistance ammeter (ZRA) -based methods are used to: a) asses the protection capability of Zinc-based sacrificial anodes; and b) experimentally determine the amount of Zinc required to cathodically protect a certain surface area of each investigated material for a specific period of time. As a further level of analysis, the manuscript investigates the protection capability of sacrificial anodes when coupled with an anodized secondary alloy. It is demonstrated that, in the case of highly alloyed Aluminums, cathodic protection can provide competing advantages with respect to conventional anodization treatments.

The manuscript investigates the use of cathodic protection -based strategies (e.g. sacrificial anodes) to prevent corrosion phenomena of two green (e.g. recycled) 43200 and 46400 Aluminum alloys. These materials are selected due to their high concentration of alloying elements (e.g. Si, Cu, Fe) that renders them as a representative example of the typical composition of secondary Aluminums. Voltammetry and zero resistance ammeter (ZRA) -based methods are used to: a) asses the protection capability of Zinc-based sacrificial anodes; and b) experimentally determine the amount of Zinc required to cathodically protect a certain surface area of each investigated material for a specific period of time. As a further level of analysis, the manuscript investigates the protection capability of sacrificial anodes when coupled with an anodized secondary alloy. It is demonstrated that, in the case of highly alloyed Aluminums, cathodic protection can provide competing advantages with respect to conventional anodization treatments.

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