This paper describes the evolution of production standards for Alloy 600 tubing, the historical performance of steam generator tubing, and the results of microstructural analyses of archive and pulled tubing samples from commercial PWRs to address these issues. Alloy 600 is a corrosion-resistant nickel-base alloy that is used in a variety of applications that require good resistance to general corrosion, high strength, and good formability. It has been used extensively for steam generator tubing in commercial nuclear power plants, and this experience led to the use of several different types of Alloy 600 material.
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After the Fukushima accident there has been a large push globally for accident tolerant fuels (ATF) to increase the grace period during an accident, that is, the time during which operators may be able to avoid major consequences by undertaking mitigating actions. At Fukushima, the oxidation of the Zircaloy cladding produced hydrogen gas, that contributed to the failure of the primary containment. A concept for ATF is to coat zirconium-based cladding with chromium to inhibit the oxidation of the cladding and reduce hydrogen production.
Mildew growth on commodity storage tanks is not a new issue within the industry and has been seen for years. However, ethanol storage tanks pose an interesting dilemma as the mildew growth on these tanks are especially aggressive and can completely deface the tanks again within months after being cleaned off. Historical knowledge of this mildew growth can be found when looking at distilleries.
MIC is a major threat to oil pipelines because it reduces the service life of pipelines and can potentially leads to catatrophes. Microbial communities commonly associated with pipeline corrosion include sulfate reducing bacteria (SRB), acid producing bacteria (APB), acetogenic bacteria and methanogens. In a field environment, SRB, APB and other microbes often live in a synergistic biofilm consortium. Sessile SRB are often the main culprit of MIC. They can utilize sulfate as the terminal electron acceptor and various carbon sources and elemental iron as electron donors. Corrosive APB biofilms are also a contributing factor in an acidic environment because they release H+ which is an oxidant.
Common materials employed in catalytic reforming unit tubes are typically resistant to carburization due to protective chromium oxide films, but under low excess oxygen conditions can become compromised and allow carbon penetration and carbide formation at the exposed surface. Embrittlement and material wastage as a result of these mechanisms causes premature failures, with production loss, in addition to shutdown maintenance and replacement costs. Carburization in this environment is simulated in this paper through a pack carburizing method designed to create an environment optimal for diffusing carbon in an ASTM 335 9Cr-1Mo tube material.
Production of highly sour oil and gas fields has increased recently, which introduces new challenges forcorrosion control. In recent years, some unexpected and unexplained pipeline failures have occurred,resulting in complex investigations and laboratory corrosion performance testing studies to assess theinhibitors that are applied in these environments. While some of these failures are due to cracking insour environments which are prevented by alternative material selection or different operation pipelinemaintenance, we were specifically looking at cases where chemical inhibitors could be used to mitigatecorrosion.
Utility water and fire water which is desalinated is supplied by Ministry of Electricity & Water (MEW) and stored in utility/fire water tank (70-T-0002). The process areas and the tanks are protected by desalinated water as fire water backed up by sea water and the buildings are protected completely by desalinated water. Buildings to be protected by desalinated fire water are fire station, maintenance & operation building, warehouse, workshop, laboratory, and administration building. DF water system used in buildings are stagnant and for the fire water in tanks are used frequently.
Scale is an adherent deposit of inorganic compounds precipitated from water onto surfaces. Most oilfield waters contain certain amounts of dissolved calcium, barium or strontium salts. The mineral scale can be formed by chemical reactions in the formation water itself, by mixing of formation water with injected seawater, or by mixing of the well streams of two incompatible oilfield waters. In carbonate reservoirs, when calcium is deposited as calcium sulfate or calcium carbonate scale, a loss of production and increased maintenance expenses can result. Therefore, effective mitigation of scaling potential is of importance to the oil producers.
Eliminating and mitigating corrosion is one of the major objectives that oil-and-gas industries are adopting to enhance and optimize the life of their assets. It is achieved by applying scientifically proven concepts that allows industries to with stand corrosion impacts, such as: cathodic protection. It is an electrochemical technique that controls a corrosion cycle by shifting the reaction and electrical potential of the metal surface, which requires protection, from anodic oxidized region to cathodic reduced region.