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99253 COMPARISON OF CORROSION OF NICKEL AND CHROMIUM

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Product Number: 51300-99253-SG
ISBN: 99253 1999 CP
Author: J. Konys, S. Fodi, A. Ruck, J. Hausselt
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Supercritical water oxidation (SCWO) is a promising and very effective method for the oxidation of organic wastes. Its high volubility for organic compounds and its special physical properties (i.e. density, viscosity) result in a key advantage over standard processes like incineration. Due to the formation of HCl during oxidation of chlorine organics, a severe corrosion attack of most of the materials has been observed. This paper describes the results of investigations of nickel base alloy G-30 and Ducrolloy, a new PM Cr-Fe alloy, exposed at 400 bar and 420°C for up to 400 hours in a CH2Cl2/H2O2 mixture with about 2000 wppm of chloride. The weight losses varied between... Keywords: SCWO, supercritical water, corrosion, oxidation, chloride, high temperature, high pressure, nickel base alloys, chromium-iron alloys
Supercritical water oxidation (SCWO) is a promising and very effective method for the oxidation of organic wastes. Its high volubility for organic compounds and its special physical properties (i.e. density, viscosity) result in a key advantage over standard processes like incineration. Due to the formation of HCl during oxidation of chlorine organics, a severe corrosion attack of most of the materials has been observed. This paper describes the results of investigations of nickel base alloy G-30 and Ducrolloy, a new PM Cr-Fe alloy, exposed at 400 bar and 420°C for up to 400 hours in a CH2Cl2/H2O2 mixture with about 2000 wppm of chloride. The weight losses varied between... Keywords: SCWO, supercritical water, corrosion, oxidation, chloride, high temperature, high pressure, nickel base alloys, chromium-iron alloys
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