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96380 MODELLING THE EFFECTS OF POROUS AND SEMI-PERMEABLE LAYERS ON CORROSION PROCESSES

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Product Number: 51300-96380-SG
ISBN: 96380 1996 CP
Author: Fraser King, Miroslav Kolar, David W. Shoesmith
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Porous and semi-permeable layers play a role in many corrosion processes. Porous layers may simply affect the rate of corrosion by affecting the rate of mass transport of reactants and products to and from the corroding surface. Semi-permeable layers can further affect the corrosion process by reacting with products and/or reactants. Reactions in semi-permeable layers include redox processes involving electron transfer, adsorption, ion-exchange and complexation reactions and precipitation/dissolution wocesses. Examples of porous and semi-permeable lay rs include non-reactive salt films, precipitate layers consisting of redox-active species in multiple oxidation states (e.g., Fe oxide films), clay and soil layers and biofilms. Examples of these various types of processes will be discussed and modelling techniques developed from studies for the disposal of high-level nuclear waste presented. Keywords: modelling, corrosion, adsorption, porous media, diffusion, redox reactions, precipitation, finite-difference models, copper, nuclear waste containers, biofilms, corrosion product, geochemistry, soils.
Porous and semi-permeable layers play a role in many corrosion processes. Porous layers may simply affect the rate of corrosion by affecting the rate of mass transport of reactants and products to and from the corroding surface. Semi-permeable layers can further affect the corrosion process by reacting with products and/or reactants. Reactions in semi-permeable layers include redox processes involving electron transfer, adsorption, ion-exchange and complexation reactions and precipitation/dissolution wocesses. Examples of porous and semi-permeable lay rs include non-reactive salt films, precipitate layers consisting of redox-active species in multiple oxidation states (e.g., Fe oxide films), clay and soil layers and biofilms. Examples of these various types of processes will be discussed and modelling techniques developed from studies for the disposal of high-level nuclear waste presented. Keywords: modelling, corrosion, adsorption, porous media, diffusion, redox reactions, precipitation, finite-difference models, copper, nuclear waste containers, biofilms, corrosion product, geochemistry, soils.
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