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96094 Detection of Localized and General Corrosion of Mild Steel in Simulated Defense Nuclear Waste Solutions Using Electrochemical Noise Analysis

Product Number: 51300-96094-SG
ISBN: 96094 1996 CP
Author: D. F. Wilson, G. E. C. Bell, G. L. Edgemon, S.J. Pawel
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Underground waste tanks fabricated kom mild steel store more than 60 million gallons of radioactive waste from 50 years of weapons production. Leaks arc suspected in a significant number of tanks. The probable modes of corrosion failures are reported to be localized corrosion (e.g. nitrate stress corrosion cracking and pitting). The use of electrochemical noise (EN) for the monitoring and detection of localized corrosion processes has received considerable attention and application over the last scvcra] years. Proof 0[ principle laboratory tests were conduclcd to verify the capability of EN evaluation to detect localized corrosion and to compare the predictions of general corrosion obtained from EN with those derived from other sources. Simple, pre–fabricated flat and U–bend specimens of’steel alloys A516–Grade 60 (UNS K02100)and A537-CL 1 (UNS K02400) were immersed in temperature controlled simulated waste solutions. The simulated waste solution was either 5M NaNO3 with 0.3M NaOH at 90°C or 11M NaNO3 with 0.15M NaOH at 95°C. The electrochemical noise activity from the spccimens was monitored and recorded for periods ranging between 140 and 240 hours. At the cnd of each test period, the specimens were metallographically examined to correlate EN data with corrosion damage. electrochemical noise, localized corrosion, pitting, nuclear waste tank corrosion, mild steel, nitrates, corrosion surveillance, and corrosion monitoring.
Underground waste tanks fabricated kom mild steel store more than 60 million gallons of radioactive waste from 50 years of weapons production. Leaks arc suspected in a significant number of tanks. The probable modes of corrosion failures are reported to be localized corrosion (e.g. nitrate stress corrosion cracking and pitting). The use of electrochemical noise (EN) for the monitoring and detection of localized corrosion processes has received considerable attention and application over the last scvcra] years. Proof 0[ principle laboratory tests were conduclcd to verify the capability of EN evaluation to detect localized corrosion and to compare the predictions of general corrosion obtained from EN with those derived from other sources. Simple, pre–fabricated flat and U–bend specimens of’steel alloys A516–Grade 60 (UNS K02100)and A537-CL 1 (UNS K02400) were immersed in temperature controlled simulated waste solutions. The simulated waste solution was either 5M NaNO3 with 0.3M NaOH at 90°C or 11M NaNO3 with 0.15M NaOH at 95°C. The electrochemical noise activity from the spccimens was monitored and recorded for periods ranging between 140 and 240 hours. At the cnd of each test period, the specimens were metallographically examined to correlate EN data with corrosion damage. electrochemical noise, localized corrosion, pitting, nuclear waste tank corrosion, mild steel, nitrates, corrosion surveillance, and corrosion monitoring.
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