The presence of hydrogen sulfide in oil and gas production is continuously increasing and the
dangerous consequences for materials through hydrogen embrittlement mechanisms are of special
concern to oil companies and pipe manufacturers. Furthermore, more severe working conditions in
terms of mechanical loads in H2S reservoirs require high grade steels. The high grade of these steels
make difficult to attain sulfide stress cracking resistance (KISSC) values as high as conventional low
steels grades. Therefore, it is of fundamental importance to evaluate the methods used to determine
the fracture resistance in sour environment.
In this work, a simplified transient approach was developed to estimate the crack growth rate in double
cantilever beam samples used in the NACE TM0177 standard method D. The evolution of the
electrochemical solution-surface system was taken into account through a variation law with the time
adjusted based on experimental results and a finite element analysis.
As a result, the instantaneously Kapplied, and consequently the KISCC, was estimated. The predictions
were compared with experimental testing results in terms of Kapplied vs. KISSC. Additionally, the effect of testing conditions, i.e. variation of H concentration with time, was assessed with the transient model.
Keywords: Sour environment, sulfide stress cracking, double cantilever beam, hydrogen diffusion