One of the major reasons why fuel-grade ethanol (FGE) is not currently transported by
pipeline is its contribution to stress corrosion cracking (SCC) of carbon steel.
Collaborative efforts have been made by several research groups to understand the
mechanism of this SCC and to devise methods of protecting carbon steel from this
environmentally assisted cracking. The focus of this paper is to discuss the effects of
ethanol chemistry on SCC of carbon steel and to provide a mechanistic picture of crack
initiation and growth in simulated fuel-grade ethanol (SFGE). Chloride content, water
content, and pHe (pH value defined in ethanol-based solvent) of the ethanol are critical
for SCC in this system. It was also found that film-related anodic dissolution controls the
cracking dynamics in SFGE during the slow strain rate test (SSRT).
Keywords: stress corrosion cracking, fuel grade ethanol, pipeline steel, passivation