Dissimilar joints are a common part of subsea oil and gas systems where clad forged fittings are
joined to clad or CRA pipe. Whilst the majority of these joints have given successful service, a small
number have failed. In the current work, environmental testing was carried out on a dissimilar joint to an
8630M forging, buttered using alloy 625. Tests were monitored using a sensitive technique in order to
capture the first moments of crack initiation and to determine the minimum threshold stress intensity
factor Kth, below which there is no environmentally assisted cracking. Two distinct initiation mechanisms
were identified; one dependent on hydrogen-charging in service (under cathodic protection) and one
not. A detailed microstructural investigation, including chemistry, structure and strain, gave insight into
the attributes of the ‘partially mixed zone’ (PMZ) immediately adjacent to the fusion boundary, on the
weld side, in which one of the failure modes occurred. The chemical and microstructural characteristic
of this PMZ are influenced by welding and postweld heat treatment (PWHT) parameters. Based on this
investigation, the potential for mitigation of cracking susceptibility by materials selection or by modifying
the welding/PWHT procedure is discussed.
Key words: Dissimilar joints, subsea, hydrogen embrittlement, cracking, microstructure