The microstructural and local corrosion characteristics of a super-austenitic stainless steel
(SASS), (Fe-24Ni-20.5Cr-6.3Mo-0.22N, UNS N08367), brazed with a commercially available Ni-based
filler alloy, (Ni-22Cr-6.5Si-3.5P) are investigated. The isolated SASS base material is intrinsically
resistant to pitting and crevice corrosion in 0.6 M NaCl solution at room temperature. Isolated braze
alloy, tested as a bead prepared at 1150 °C for 60 minutes in a vacuum furnace, without the diffusive
egress of melting point depressants (MPDs) exhibited critical potentials for localized corrosion in 0.6 M
NaCl well below that of the SASS. This is due to both the low pitting resistance equivalency number
(PREN) of the Ni-Cr solid solution and the loss of beneficial Cr due to formation of silicide and
phosphide phases, enabled by the presence of these MPDs.