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03451 EFFECT OF TIN CONTENT ON THE CORROSION OF ZIRCONIUM 702 IN SULFURIC ACID

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Product Number: 51300-03451-SG
ISBN: 03451 2003 CP
Author: Derrill R. Holmes
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Laboratory testing was used to demonstrate the differences in corrosion rate of typical zirconium 702 (R60702) containing approximately 2400 ppm tin, and low-tin zirconium 702 containing approximately 1400 ppm tin. Sample material was heat-treated at 770ºC for 1 hour. Standard immersion testing was conducted in 60-70% sulfuric acid at boiling temperatures. Autoclave testing was performed at the same concentrations of acid, but at temperatures up to 180°C. Updated 5 mpy isocorrosion curves for zirconium in sulfuric acid are presented. The effect of heat treatment on corrosion resistance in sulfuric acid applications is discussed. Keywords: Zircadyne-702®, zirconium, tin, sulfuric acid, heat-treatment, corrosion
Laboratory testing was used to demonstrate the differences in corrosion rate of typical zirconium 702 (R60702) containing approximately 2400 ppm tin, and low-tin zirconium 702 containing approximately 1400 ppm tin. Sample material was heat-treated at 770ºC for 1 hour. Standard immersion testing was conducted in 60-70% sulfuric acid at boiling temperatures. Autoclave testing was performed at the same concentrations of acid, but at temperatures up to 180°C. Updated 5 mpy isocorrosion curves for zirconium in sulfuric acid are presented. The effect of heat treatment on corrosion resistance in sulfuric acid applications is discussed. Keywords: Zircadyne-702®, zirconium, tin, sulfuric acid, heat-treatment, corrosion
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