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03351 FAILURE OF UNS N10276 REACTOR IN SUPERCRITICAL WATER SERVICE

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Product Number: 51300-03351-SG
ISBN: 03351 2003 CP
Author: D. W. Alley, S. A. Bradley
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Catalytic reactions in supercritical water represent a potential alternative to conventional hydroprocessing of heavy oils. A pilot plant with a reactor constructed from UNS N10276 was developed to test this possibility. Rapid failure of the reactor due to intergranular corrosion was observed in the reactor at a point where the temperature of the water feed was in the high subcritical range. The cause for the corrosion was not determined, however, it appears to be related to a proprietary carbonate in the water feed. Keywords: supercritical water, corrosion, UNS N10276, heavy oils, stainless steel
Catalytic reactions in supercritical water represent a potential alternative to conventional hydroprocessing of heavy oils. A pilot plant with a reactor constructed from UNS N10276 was developed to test this possibility. Rapid failure of the reactor due to intergranular corrosion was observed in the reactor at a point where the temperature of the water feed was in the high subcritical range. The cause for the corrosion was not determined, however, it appears to be related to a proprietary carbonate in the water feed. Keywords: supercritical water, corrosion, UNS N10276, heavy oils, stainless steel
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