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02180 CORROSION MECHANISMS AND ELECTROCHEMICAL BEHAVIOUR OF THERMAL SPRAY COATINGS (WC-Cr-Ni AND WCCrC)

Product Number: 51300-02180-SG
ISBN: 02180 2002 CP
Author: V A D Souza and A Neville
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In this experimental study the corrosion characteristics (rates and mechanisms) of two thermally-sprayed cermet coatings have been examined in a static saline environment (synthetic seawater). The coatings have complex microstructures where the ceramic hard-phase constituents are embedded in a metallic matrix. Their electrochemical response during accelerated corrosion DC polarisation tests reflects this complexity. The test protocol has enabled the mechanisms of corrosion occurring on the WC/CrC cermet and the WC-Cr-Ni cermet to be compared and contrasted. A 'critical' temperature has been defined for the WC-Cr-Ni coating similar to the critical pitting temperature (CPT) for stainless steels. Electrochemical behavior, which can not be simply described as truly 'passive' behavior, is displayed by the WC/CrC coating and such a well-defined 'critical' temperature is not apparent. The contrasting mechanisms of corrosion, identified during post-test examination, can be correlated to the contrasting electrochemical response. Keywords: corrosion, thermal spray, coating, cermet, electrochemistry.
In this experimental study the corrosion characteristics (rates and mechanisms) of two thermally-sprayed cermet coatings have been examined in a static saline environment (synthetic seawater). The coatings have complex microstructures where the ceramic hard-phase constituents are embedded in a metallic matrix. Their electrochemical response during accelerated corrosion DC polarisation tests reflects this complexity. The test protocol has enabled the mechanisms of corrosion occurring on the WC/CrC cermet and the WC-Cr-Ni cermet to be compared and contrasted. A 'critical' temperature has been defined for the WC-Cr-Ni coating similar to the critical pitting temperature (CPT) for stainless steels. Electrochemical behavior, which can not be simply described as truly 'passive' behavior, is displayed by the WC/CrC coating and such a well-defined 'critical' temperature is not apparent. The contrasting mechanisms of corrosion, identified during post-test examination, can be correlated to the contrasting electrochemical response. Keywords: corrosion, thermal spray, coating, cermet, electrochemistry.
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