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01301 REFERENCE HALF-CELLS FOR THE OCEAN ENVIRONMENT

Product Number: 51300-01301-SG
ISBN: 01301 2001 CP
Author: M.H. PETERSON, A.I. KAZNOFF, K.E. LUCAS AND E.A. HOGAN
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Reference half-cells are widely used by corrosion scientists and engineers but are poorly understood by many users without a background in chemistry. This review covers the basic chemical rationale for reference half-cell, and the conventions established for their use. The problems of electrochemical potential measurements in sea water systems, some solutions to these problems, and the reproducibility Ag/AgCl half-cells are discussed. Preliminary studies of Will self generated hydrogen electrodes are also included. Keywords: half-cells, reference electrodes, seawater, Ag/AgCl, hydrogen cell
Reference half-cells are widely used by corrosion scientists and engineers but are poorly understood by many users without a background in chemistry. This review covers the basic chemical rationale for reference half-cell, and the conventions established for their use. The problems of electrochemical potential measurements in sea water systems, some solutions to these problems, and the reproducibility Ag/AgCl half-cells are discussed. Preliminary studies of Will self generated hydrogen electrodes are also included. Keywords: half-cells, reference electrodes, seawater, Ag/AgCl, hydrogen cell
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