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Biocides are used in hydraulic fracturing operations to control the growth of contaminant microorganisms that lead to corrosion, souring, and conductivity loss.1,2 A variety of biocides are utilized and can be classified by mechanism of action, speed of kill, and the length of residual activity.In general, rapid-acting biocides such as chlorine dioxide (ClO2) and DBNPA (2,2-dibromo-3- nitrilopropionamide) inactivate bacteria quickly but have little to no residual activity. Glutaraldehyde (Glut) reacts more slowly and provides some residual activity, particularly at lower wellbore or reservoir temperatures.
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