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As far as the automotive sector is concerned, braking discs (BDs) are objects usually made of Grey Cast-Iron (GCI), i.e. a material exhibiting overall good mechanical properties and castability, but poor corrosion resistance. In particular, looking at the standard working conditions of a disc brake system, several environmental factors can cause and enhance GCI corrosion phenomena, such as: i) atmospheric moisture; i) ionic species contained in aerosols (e.g., chlorides and sulfates); iii) air differential corrosion caused by discs surface soiling by mud or other materials; and iv) galvanic coupling between the rotor and the braking pads.