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The interaction of metals and alloys with aqueous environments is ubiquitous, leading to oxide formation (passivity) or corrosion in many cases. Although these phenomena have significant importance across various industries and domains of materials science, the fundamental atomic-scale mechanisms by which corrosion and oxide formation operate are still unclear. Oxide films can have complex chemistry and texture, especially at the metal-oxide interface which acts as the primary barrier from solution interaction. The Zr-H2O system has industrial and academic interest due to its use in nuclear reactors.
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