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Alloy 600 (Ni-16Cr-9Fe) is well known to exhibit intergranular corrosion and intergranular stress corrosion cracking (IGSCC) upon exposure to high temperature water environments, including those found in service environments of pressurized water reactors (PWR). While the higher Cr content alloy 690 exhibits superior IGSCC resistance in these environments, alloy 600 is still in use at many light water reactor plants. Part of the difficulty in assessing alloy 600 performance is the significant variability in behavior from heat to heat, both from the standpoint of initial alloy chemistry and the subsequent thermomechanical treatment of the material.
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This paper describes the evolution of production standards for Alloy 600 tubing, the historical performance of steam generator tubing, and the results of microstructural analyses of archive and pulled tubing samples from commercial PWRs to address these issues. Alloy 600 is a corrosion-resistant nickel-base alloy that is used in a variety of applications that require good resistance to general corrosion, high strength, and good formability. It has been used extensively for steam generator tubing in commercial nuclear power plants, and this experience led to the use of several different types of Alloy 600 material.