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Resistance of S30400 and S31600 SSs to chloride-induced crevice corrosion was assessed in a wide range of temperatures and chloride concentrations. Repassivation potential of S30400 SS decreased with increasing chloride & temperatures from 0 to 60ºC, and it a constant value in the range from 60 to 90ºC regardless of chloride.
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A Sulfuric Acid Alkylation [SAA] unit in a refinery converts olefins and butane to high octane alkylate using highly concentrated sulfuric acid as a catalyst. The function of this Sulfuric Acid Regeneration [SAR] unit is to regenerate spent sulfuric acid from alkylation process into clean sulfuric acid of 99.2% concentration, which is then recycled back into the SAA unit. The process of SAR can be classified in to following four steps:
• Formation of SO2 by the decomposition of Spent acid and combustion of H2S.• Cooling and Purification of the SO2• Conversion of SO2 to SO3• Absorption of SO2 in H2SO4