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This paper provides an introduction on carbonate cracking and Los Angeles refinery’s recent experience with this corrosion mechanism. Also included in this paper is the methodology used for developing a risk assessment for equipment and piping susceptible to carbonate stress corrosion cracking in a fluid catalytic cracking unit (FCCU) gas plant.
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Cases where alkaline-carbonate stress corrosion cracking (ACSCC) occurred, including a cold wall Fluid Catalytic Cracking (FCC) Unit regenerator and a mercaptan oxidation unit. This paper discusses work done to monitor on-going ACSCC risks through sour water sampling, chemical analysis, and ionic modeling.