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Pyrolysis processes of post-consumer plastics are a promising chemical recycling route and a good alternative to disposal. Nevertheless, these processes are challenging for metallic materials since chlorine containing materials or biological components inside the feedstock can yield HCl and H2S, respectively, during cracking. In combination with high temperatures of the reactor zone metallic construction materials can be attacked by high-temperature corrosion.
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A major fire in a Reactor Effluent Air Cooler (REAC) of the Hydrocracker Unit (HCU). Visual inspection was made on the failed portion. Metallurgical investigation, macrostructural and microstructural analysis, Scanning Electron Microscopy, and Energy Dispersive x-ray Spectroscopy was conducted on the failed air cooler.
UNS S31400 stainless steel was tested as a reactor material for a thermal cracking process of agricultural, silvicultural, industrial and anthropogenic resources containing HCl. This material was chosen as it offers proper corrosion resistance in hot gases besides a good price and a high availability.