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Initial investigations described at Corrosion 2011. This paper reports on development of a micelle detection instrument. Criteria for interpreting the presence of micelles will be reported and results of a simulated field study to investigate the link between inhibitor micelle presence and corrosion rate. Together with results from real field samples, this data will be presented as development of a new tool for field analysis of brines
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Methodology and approach used to characterize micellization and adsorption related parameters for an individual corrosion inhibitor components; specifically, data for a homologous quaternary amine series.
Rotating cylinder electrode (RCE) methodology with electrochemical impedance spectroscopy (EIS) measurement was applied to study the inhibition behavior of quaternary ammonium compounds on CO2 corrosion of X65 carbon steel.
As environmentally friendly coatings, inks, and adhesive systems have evolved; additives have also evolved in chemistry, structure and effectiveness. This overview strives to present these new additive technologies in three areas: surfactants, dispersants, and defoamers. The chemical nature of these additives and subsequent performance in a variety of systems will be described.
Corrosion inhibitors provide a critical barrier to internal corrosion, presenting the most cost-effective form of mitigation and enabling operators to use carbon steel where it would otherwise be impractical. The correct selection and validation of inhibitors is essential to ensure successful field deployment, providing safe and reliable operation. However, the selection and optimization of a corrosion inhibitor for a particular field application is not trivial.
In the first paper, a mixture design matrix of a homologous series of alkyldimethylbenzylammonium chlorides (BAC) was used to assess the performance and facilitate optimization of a mixed surfactant corrosion inhibitor system based on surface coverage and steady state inhibited corrosion rate.1 In this second paper, the approach is extended to include adsorption kinetic analysis, as demonstrated in Woollam and Betancourt for a first-order Langmuir kinetic model.2
Corrosion inhibitors are used to prevent pipeline corrosion in oil and gas industry. The evaluation of corrosion inhibitors is one of the most important tasks for the corrosion engineers. Corrosion of the metal is suppressed by the inhibitor adsorption on the metal surface. Active ingredients of corrosion inhibitors are, in general, surfactants. A surfactant can adsorb on the internal metal surface of piping and makes a hydrophobic film preventing the contact of water with the metal surface.