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It is well known that H2S promotes hydrogen entry into steels that may result in many types of steel failures. This paper examines the influence of traces of oxygen on corrosion and hydrogen charging of steel in an H2S containing environment.
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Corrosion experiments on X65 carbon steel in water-saturated supercritical CO2 (SC-CO2) and under-saturated SC-CO2 conditions at 80 bar and 35°C in the absence and presence of various combinations of NO2 and O2 ranging from 0-100 ppm and 0-1000 ppm, respectively.
Results from novel transparent autoclave experiments. Carbon steel corrosion coupons were exposed to impurities levels within established specifications at simulated transport conditions (25 °C and 10 MPa of CO2).
This paper re-examines most public and in-house corrosion data on the effects of six typical impurities to advance the fundamental understanding of how pipeline steels corrode in sc-CO2 environments and identify knowledge gaps for further investigations.
Over the years, the supercritical carbon dioxide (s−CO2) Brayton cycle has been developed as a promising working fluid to replace supercritical water (s−H2O) Rankine cycle. It could be used in various energy systems, including Generation IV nuclear reactors, concentrated solar power plants, fossil fuel thermal power plants, waster heat recovery, etc. due to its merits of high thermal efficiency, simple physical footprint, compact equipment size, high flexibility on operation, simple layout, compact turbomachinery.1