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Brief descriptions of the mechanisms of common types of corrosion attacks in petrochemical and refinery environments viz. Wet H2S, Caustic, Amine, Carbonate corrosion and cracking.
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This paper summarizes an experimental program that studied the impact of aqueous solutions containing various concentrations of H2S at varying total pressures established by the pressurization of the single aqueous phase.
As environmental sulfur limits become more stringent, there has been a recent surge in preferential and localized corrosion in amine units. This has occurred even with HIC (Hydrogen Induced Cracking) resistant steels and in equipment where velocity limits are not exceeded.Amine absorbers and associated rich amine piping particularly around the welds, downcomers and other turbulent locations are particularly vulnerable.