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The Effect Of Interactions Between Cathodic Protection Potential And Stress Concentration On Hydrogen Embrittlement Of Precipitation-Hardened Nickel Alloys

Product Number: 51321-16663-SG
Author: Imran Bhamji; Kasra Sotoudeh; Menno Hoekstra; Herman Amaya; Bryan Fahimi
Publication Date: 2021
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Precipitation-hardened nickel alloys (PHNAs) are widely used for demanding oil and gas subsea
applications, because of their high strength and corrosion resistance. However, several failures were
associated with hydrogen embrittlement, under cathodic protection (CP), as subsea CP systems can
provide a source of atomic hydrogen, which can diffuse into the material and compromise its
toughness. The risk of hydrogen embrittlement might be reduced if CP systems were appropriately
designed, e.g. more positive CP potentials could locally be applied to CRA components. Whilst tailored
CP profiles will remain a practical challenge, the relationship between the CP potential and localised
loading, due to the presence of stress raisers, is yet to be established.
This paper aims to address whether there is a threshold potential, above which embrittlement will not
occur, and whether this threshold will be a function of stress intensity/concentration factor. This was
explored through conducting slow strain rate tensile (SSRT) and incremental step load (ISL) testing on
UNS(1) N07716, which has previously been associated with failures, at potentials between -750 and
-1050mVAg/AgCl, on plain-sided specimens. Additional fracture-toughness-based testing, using single
edge notch bend (SENB) specimens, was undertaken to understand if the stress intensity (associated
with a fatigue pre-crack), can increase susceptibility to embrittlement.

Precipitation-hardened nickel alloys (PHNAs) are widely used for demanding oil and gas subsea
applications, because of their high strength and corrosion resistance. However, several failures were
associated with hydrogen embrittlement, under cathodic protection (CP), as subsea CP systems can
provide a source of atomic hydrogen, which can diffuse into the material and compromise its
toughness. The risk of hydrogen embrittlement might be reduced if CP systems were appropriately
designed, e.g. more positive CP potentials could locally be applied to CRA components. Whilst tailored
CP profiles will remain a practical challenge, the relationship between the CP potential and localised
loading, due to the presence of stress raisers, is yet to be established.
This paper aims to address whether there is a threshold potential, above which embrittlement will not
occur, and whether this threshold will be a function of stress intensity/concentration factor. This was
explored through conducting slow strain rate tensile (SSRT) and incremental step load (ISL) testing on
UNS(1) N07716, which has previously been associated with failures, at potentials between -750 and
-1050mVAg/AgCl, on plain-sided specimens. Additional fracture-toughness-based testing, using single
edge notch bend (SENB) specimens, was undertaken to understand if the stress intensity (associated
with a fatigue pre-crack), can increase susceptibility to embrittlement.

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Non-metallic Applications in Oil & Gas Industry

Product Number: MPWT19-14383
Author: Mohamed Al Ghosain, Ali Azman Faheem, Ullah Mohamed, Zohair Zaki
Publication Date: 2019
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Corrosion, either internal or external, along with other types of defects on pipelines eventually lead to leaks without proper treatment. This gives rise to several issues, including environmental and safety hazards, and in case of pipe leaks in a plant, a loss of the efficiency of the process or, ultimately, failure of the process. Replacing the corroded pipelines (piping) can be difficult, costly and time consuming especially for plant. A required shutdown causes major economic loss. Thus, instead of a replacement of the defected pipelines, the installation of online repair is a better option.
Repairs of pipelines include metallic and non-metallic repairs. Metallic repairs generally require welding or hot works which is not suitable for online repair of pipes containing hydrocarbons. In such cases the use of non-metallic composite repairs is the optimum solution. A non-metallic composite repair system is a system used to reinforce structures using a fiber equipped with a thermoset epoxy system. The epoxy system consists of a hardener and a resin which, after mixing, become solid through a polymerization reaction after a short duration of time, a process that is called curing. Depending on the temperature, the duration of time changes in an inverse relation. The higher the temperature, the smaller the duration of time needed for curing. This system can be used to reinforce pipelines with both external and internal corrosion and it can be used on Straight Pipes, Tees, Elbows, Flanges and weld joints. The repair system can also be installed online without the need for a shutdown in a short amount of time and a small requirement of labor intensity, making it cost effective. It is also environmentally friendly. In this paper we are going to present cases that were resolved by our company that demonstrate how successful these non-metallic composite repairs are and how diverse their applications can be