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13Cr-5Ni-2Mo type Super Martensitic stainless steels referred to as SMSS-13Cr type grades can provide good general corrosion resistance such as in high CO2 environments combined with higher strengths and excellent toughness2 making them a prospective material choice for long term downhole completion equipment depending on actual well conditions. One of the main limiting factors for the use of SMSS-13Cr type grades is the Sulfide Stress Cracking (SSC) resistance in presence of H2S in downhole well conditions. Therefore, a good understanding of this behavior is essential to facilitate the material selection process.
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Steel pipelines are sometimes subjected to demanding sour environments resulting from the presence of high H2S contents. Pipeline materials, therefore, must be resilient against sulfide stress cracking (SSC) which is caused by H2S. Beginning in the 1980s, thermo-mechanically controlled processed (TMCP) steels have been widely used for the manufacturing of large-diameter sour service pipelines. The failure of the Kashagan pipelines in 2013 raised concern regarding the use of TMCP steels in sour environments. These concerns arise from the potential for local hard zones (LHZs) to be produced on the surface of the line pipe during TMCP processes, ultimately leading to through-wall SSC failures. In the present study, several X60 - X65 TMCP steels (both with and without LHZs) have been tested under different Region 3 (R3) conditions in the NACE MR0175/ISO15156-2 pH-H2S partial pressure diagram. It can be concluded that the presence of LHZs increases TMCP steels’ sour cracking susceptibility; however, TMCP steels without LHZs pass the SSC tests at even the most severe R3 environments. Traditional HRC or HV10 testing are not able to detect LHZs, and so lower load HV 0.5 or HV 0.1 tests are necessary. For TMCP steels, the current R3 may be further divided into R3-a and R3-b sub-regions. The sour cracking severity of R3-a is less than that of R3-b. Additional actions, like enhanced mill qualification of the TMCP plate, should be considered to ensure that no LHZs exist in steels to be utilized in R3-b environments.
High Pressure and High Temperature wells are very critical and require special attention to avoid well integrity issues. High pressure requests the use of very high strength low alloyed steels, above 965 MPa (140 ksi), while even trace of hydrogen sulfide implies significant partial pressures of H2S, much higher than the limit of 0.05 psi (3.5 mbar) provided by NACE MR0175 / ISO 15156 standard. Consequently, and despite a high temperature that reduces the risk of cracking, it is crucial to assess the resistance to Sulfide Stress Cracking of materials. However low alloyed steels experience high corrosion rates when exposed to standardized test solutions at elevated temperatures, leading to difficulties of controlling the mechanical stress loading, with a load rising in NACE TM0177 Method A and declining in four-points bending test. In addition, close attention shall be paid to both the evolution of the mechanical properties of the materials with the temperature and the appropriate sequence of sour gas introduction with regards to the temperature control. This paper discusses the most appropriate testing protocol for overcoming these issues and provides experimental results obtained in the frame of the qualification of 965 MPa (140 ksi) controlled yield grade for HPHT applications.